Carbohydrates as building blocks of privileged ligands
作者： Vincenzo Benessere , Raffaella Del Litto , Antonella De Roma , Francesco Ruffo
DOI: 10.1016/J.CCR.2009.05.001
关键词:
摘要: Abstract “Privileged ligands” are chiral auxiliaries of wide applicability in asymmetric catalysis. In the previous decades, their effective three-dimensional structures have often been reproduced by using building blocks from a “chiral pool”, such as carbohydrates. This strategy has provided unique ligand moieties which combine performance “privileged with increased flexibility and accessibility. review gives an overview research within this field, giving emphasis to best results obtained each type.
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