Synthesis of Trisubstituted Imidazoles Using Lewis and Bronsted Acid Catalysts

作者: Rahim Hekmatshoar , Hajar Jahanbakhshi , Reyhane Rahnamafar , Farnoosh Mousavizadeh

DOI:

关键词:

摘要: An efficient and one-pot method for the preparation of trisubstituted imidazoles by condensation benzil, different aldehydes ammonium acetate in presence a catalytic amount NiSO4.7H2O or H3BO3 under conditions is reported. Key Words : T risubstituted imidazoles, Multi-component reactions, NiSO4.7H2O, H3BO3,                                     reactions,  solid acid catalysts.

参考文章(23)
K. Sivakumar, A. Kathirvel, A. Lalitha, Simple and efficient method for the synthesis of highly substituted imidazoles using zeolite-supported reagents Tetrahedron Letters. ,vol. 51, pp. 3018- 3021 ,(2010) , 10.1016/J.TETLET.2010.04.013
Jingping Liu, Jingbo Chen, Jingfeng Zhao, Yuanhong Zhao, Hongbin Zhang, A Modified Procedure for the Synthesis of 1‐Arylimidazoles. ChemInform. ,vol. 35, ,(2004) , 10.1002/CHIN.200415105
Biswanath Das, Chithaluri Sudhakar, Yallamalla Srinivas, Efficient Synthesis of 5-Substituted 2,3-Diphenyl and 5-Substituted 1-Aryl-2,3-diphenyl Imidazoles Using Polyethylene Glycol Synthetic Communications. ,vol. 40, pp. 2667- 2675 ,(2010) , 10.1080/00397910903318633
Jiro Tsuji, Kiyomi Sakai, Hisao Nemoto, Hideo Nagashima, Iron and copper catalyzed reaction of benzylamine with carbon tetrachloride: facile formation of 2,4,5- triphenylimidazoline derivatives Journal of Molecular Catalysis. ,vol. 18, pp. 169- 176 ,(1983) , 10.1016/0304-5102(83)80116-3
Hilmar Weinmann, Michael Harre, Klaus Koenig, Erik Merten, Ulf Tilstam, Efficient and environmentally friendly synthesis of 2-amino-imidazole Tetrahedron Letters. ,vol. 43, pp. 593- 595 ,(2002) , 10.1016/S0040-4039(01)02226-2
Francis R. Japp, H. H. Robinson, Constitution des Lophins und des Amarins European Journal of Inorganic Chemistry. ,vol. 15, pp. 1268- 1270 ,(1882) , 10.1002/CBER.188201501272
Shapi A. Siddiqui, Umesh C. Narkhede, Sanjay S. Palimkar, Thomas Daniel, Rajgopal J. Lahoti, Kumar V. Srinivasan, Room temperature ionic liquid promoted improved and rapid synthesis of 2,4,5-triaryl imidazoles from aryl aldehydes and 1,2-diketones or α-hydroxyketone Tetrahedron. ,vol. 61, pp. 3539- 3546 ,(2005) , 10.1016/J.TET.2005.01.116
Mazaahir Kidwai, Poonam Mothsra, Vikas Bansal, Rishi K. Somvanshi, Abdul S. Ethayathulla, Sharmistha Dey, Tej P. Singh, One-pot synthesis of highly substituted imidazoles using molecular iodine : A versatile catalyst Journal of Molecular Catalysis A-chemical. ,vol. 265, pp. 177- 182 ,(2007) , 10.1016/J.MOLCATA.2006.10.009