Synthesis and x-ray data of a stable in air crystalline modification of chromium(II) phthalocyanine (Cr-α-Pc)

作者: C. Ercolani , C. Neri , P. Porta

DOI: 10.1016/S0020-1693(00)93214-6

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摘要: Abstract When the β modification of chromium(II) phthalocyanine is sublimed under specified conditions, a purple-red microcrystalline product obtained which, unlike starting compound does not react with air. This sublimate has been identified as α form by its analytical data and IR spectrum well on basis isomorphism forms iron(II) cobalt(II) phthalocyanine. The different stability ain air two can be reasonably explained their crystal features.

参考文章(8)
Michio Ashida, Natsu Uyeda, Eiji Suito, Unit Cell Metastable-form Constants of Various Phthalocyanines Bulletin of the Chemical Society of Japan. ,vol. 39, pp. 2616- 2624 ,(1966) , 10.1246/BCSJ.39.2616
J. Monteath Robertson, Ida Woodward, 37. An X-ray study of the phthalocyanines. Part III. Quantitative structure determination of nickel phthalocyanine Journal of The Chemical Society (resumed). pp. 219- 230 ,(1937) , 10.1039/JR9370000219
J. A. Elvidge, A. B. P. Lever, 245. Metal chelates. Part II. Phthalocyanine–chromium complexes and perpendicular conjugation J. Chem. Soc.. ,vol. 0, pp. 1257- 1265 ,(1961) , 10.1039/JR9610001257
E. G. Meloni, L. R. Ocone, B. P. Block, PHTHALOCYANINATO(2-)CHROMIUM(III) PHOSPHINATES. Inorganic Chemistry. ,vol. 6, pp. 424- 425 ,(1967) , 10.1021/IC50048A062
P. A. Barrett, C. E. Dent, R. P. Linstead, 382. Phthalocyanines. Part VII. Phthalocyanine as a co-ordinating group. A general investigation of the metallic derivatives Journal of the Chemical Society (Resumed). pp. 1719- 1736 ,(1936) , 10.1039/JR9360001719
Bertold Honigmann, Horst-Udo Lenné, Rudolf Schrödel, Beziehungen zwischen den Strukturen der Modifikationen des Platin- und Kupferphthalocyanins und einiger Chlorderivate* Zeitschrift Fur Kristallographie. ,vol. 122, pp. 185- 205 ,(1965) , 10.1524/ZKRI.1965.122.3-4.185
J. Monteath Robertson, Ida Woodward, 7. An X-ray study of the phthalocyanines. Part IV. Direct quantitative analysis of the platinum compound Journal of the Chemical Society (Resumed). pp. 36- 48 ,(1940) , 10.1039/JR9400000036