Copper(II)-Catalyzed Selective Reductive Methylation of Amines with Formic Acid: An Option for Indirect Utilization of CO2
作者： Chang Qiao , Xiao-Fang Liu , Xi Liu , Liang-Nian He
DOI: 10.1021/ACS.ORGLETT.7B00551
关键词:
摘要: … above-mentioned reaction with formic acid as C1 source and … N-methylation of amines/imine with formic acid as renewable … N-methylation of amines using formic acid and hydrosilane. …
acs.org
sci-hub.se 参考文章(43)
Roland Fornika, Helmar Görls, Bernd Seemann, Walter Leitner, Complexes [(P2)Rh(hfacac)](P2= bidentate chelating phosphane, hfacac = hexafluoroacetylacetonate) as catalysts for CO2 hydrogenation: correlations between solid state structures, 103Rh NMR shifts and catalytic activities Journal of The Chemical Society, Chemical Communications. pp. 1479- 1481 ,(1995) , 10.1039/C39950001479
Sebastian Rendler, Martin Oestreich, Polishing a Diamond in the Rough: “Cu ? H” Catalysis with Silanes Angewandte Chemie. ,vol. 46, pp. 498- 504 ,(2007) , 10.1002/ANIE.200602668
Kseniya Revunova, Georgii I. Nikonov, Base-catalyzed hydrosilylation of ketones and esters and insight into the mechanism. Chemistry: A European Journal. ,vol. 20, pp. 839- 845 ,(2014) , 10.1002/CHEM.201302728
Seung���Hwan Cho, Ji���Young Kim, S.���Yunmi Lee, Sukbok Chang, Silver‐Mediated Direct Amination of Benzoxazoles: Tuning the Amino Group Source from Formamides to Parent Amines Angewandte Chemie. ,vol. 48, pp. 9127- 9130 ,(2009) , 10.1002/ANIE.200903957
Ken Motokura, Daiki Kashiwame, Akimitsu Miyaji, Toshihide Baba, None, Copper-catalyzed formic acid synthesis from CO2 with hydrosilanes and H2O. Organic Letters. ,vol. 14, pp. 2642- 2645 ,(2012) , 10.1021/OL301034J
Keith G. Andrews, Declan M. Summers, Liam J. Donnelly, Ross M. Denton, Catalytic reductive N-alkylation of amines using carboxylic acids Chemical Communications. ,vol. 52, pp. 1855- 1858 ,(2016) , 10.1039/C5CC08881J
Thanh V. Q. Nguyen, Woo‐Jin Yoo, Shū Kobayashi, Chelating Bis(1,2,3-triazol-5-ylidene) Rhodium Complexes: Versatile Catalysts for Hydrosilylation Reactions Advanced Synthesis & Catalysis. ,vol. 358, pp. 452- 458 ,(2016) , 10.1002/ADSC.201500875
Paolo Marchini, Gaetano Liso, Antonia Reho, Felice Liberatore, Franco Micheletti Moracci, Sodium borohydride-carboxylic acid systems. Useful reagents for the alkylation of amines Journal of Organic Chemistry. ,vol. 40, pp. 3453- 3456 ,(1975) , 10.1021/JO00911A038
H. T. Clarke, H. B. Gillespie, S. Z. Weisshaus, The Action of Formaldehyde on Amines and Amino Acids1 Journal of the American Chemical Society. ,vol. 55, pp. 4571- 4587 ,(1933) , 10.1021/JA01338A041
Toni T. Metsänen, Martin Oestreich, Temperature-Dependent Chemoselective Hydrosilylation of Carbon Dioxide to Formaldehyde or Methanol Oxidation State Organometallics. ,vol. 34, pp. 543- 546 ,(2015) , 10.1021/OM501279A