Cubane and Incomplete Cubane-Type Molybdenum and Tungsten Oxo/Sulfido Clusters
作者： Takashi Shibahara
DOI: 10.1016/S0898-8838(08)60006-9
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摘要: Publisher Summary This chapter presents a survey on the structural aspect of cubane-type compounds with Mo 4 O 4– n ,S ( = 0, 3, or 4) cores and incomplete 3 S, W S (n 0-4) cores. Compounds mixed-metal MS (M metals) are also discussed in chapter. Notes synthetic procedures presented. Although solid-state chemistry molybdenum has been developed with, for example, infinite repeat MO units, only discrete these presented this review organized primarily according to number metals (three four) secondarily bridging sulfur atoms. In contrast situation, many clusters – have prepared structures determined by X-ray structure analyses. The results obtained There three kinds series complexes. is single cubane-type, , double MMS sandwich -S .
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