Electrodeposition of ternary CuxSnySz thin films for photovoltaic applications
作者： Francesco Di Benedetto , Ilaria Bencistà , Stefano Caporali , Serena Cinotti , Antonio De Luca
DOI: 10.1002/PIP.2386
关键词:
摘要: We exploited alternated electrodeposition of Cu, Sn and S to obtain CuxSnySz thin films. These materials are kesterite-type chalcogenides that have attracted a relevant interest from worldwide researchers as low cost high conversion efficiency solar cell devices. Films were grown on silver substrate, controlling the growth electrodeposited structures at nanometric level. The obtained films characterized by diffuse reflectance spectroscopy, voltammetric stripping atomic force microscopy. Experimental bandgap energies resulted linearly modulated changes chemical composition thickness. On basis these results, we candidate room temperature method for technology with energy investment negligible environmental impact. Copyright © 2013 John Wiley & Sons, Ltd.
sci-hub.se 参考文章(36)
John L. Stickney, Electrochemical Atomic Layer Epitaxy ,(1997)
Changzheng Wu, Zhenpeng Hu, Chengle Wang, Hua Sheng, Jinlong Yang, Yi Xie, Hexagonal Cu2SnS3 with metallic character: Another category of conducting sulfides Applied Physics Letters. ,vol. 91, pp. 143104- ,(2007) , 10.1063/1.2790491
Maria Luisa Foresti, Ferdinando Capolupo, Massimo Innocenti, Francesca Loglio, Visual detection of crystallographic orientations of face-centered cubic single crystals Crystal Growth & Design. ,vol. 2, pp. 73- 77 ,(2002) , 10.1021/CG015537I
M. Innocenti, S. Cattarin, M. Cavallini, F. Loglio, M.L. Foresti, Characterisation of thin films of CdS deposited on Ag(111) by ECALE. A morphological and photoelectrochemical investigation Journal of Electroanalytical Chemistry. ,vol. 532, pp. 219- 225 ,(2002) , 10.1016/S0022-0728(02)00846-X
S. Schorr, Structural aspects of adamantine like multinary chalcogenides Thin Solid Films. ,vol. 515, pp. 5985- 5991 ,(2007) , 10.1016/J.TSF.2006.12.100
Kazuo Jimbo, Ryoichi Kimura, Tsuyoshi Kamimura, Satoru Yamada, Win Shwe Maw, Hideaki Araki, Koichiro Oishi, Hironori Katagiri, Cu2ZnSnS4-type thin film solar cells using abundant materials Thin Solid Films. ,vol. 515, pp. 5997- 5999 ,(2007) , 10.1016/J.TSF.2006.12.103
P A Fernandes, P M P Salomé, A F da Cunha, A study of ternary Cu2SnS3 and Cu3SnS4 thin films prepared by sulfurizing stacked metal precursors Journal of Physics D. ,vol. 43, pp. 215403- ,(2010) , 10.1088/0022-3727/43/21/215403
M Innocenti, F Forni, G Pezzatini, R Raiteri, F Loglio, M.L Foresti, Electrochemical behavior of As on silver single crystals and experimental conditions for InAs growth by ECALE Journal of Electroanalytical Chemistry. ,vol. 514, pp. 75- 82 ,(2001) , 10.1016/S0022-0728(01)00620-9
F. Loglio, M. Innocenti, A. Jarek, S. Caporali, I. Pasquini, M.L. Foresti, Nickel sulfur thin films deposited by ECALE: Electrochemical, XPS and AFM characterization Journal of Electroanalytical Chemistry. ,vol. 638, pp. 15- 20 ,(2010) , 10.1016/J.JELECHEM.2009.10.027
M. L. Foresti, G. Pezzatini, M. Cavallini, G. Aloisi, M. Innocenti, R. Guidelli, Electrochemical Atomic Layer Epitaxy Deposition of CdS on Ag(111): An Electrochemical and STM Investigation Journal of Physical Chemistry B. ,vol. 102, pp. 7413- 7420 ,(1998) , 10.1021/JP9811777