Solvent-induced stabilization of the naphthalene anion by water molecules: A negative cluster ion photoelectron spectroscopic study
作者： Svetlana A. Lyapustina , Shoujun Xu , J. Michael Nilles , Kit H. Bowen
DOI: 10.1063/1.481237
关键词:
摘要: We show that (a) only a single water molecule is needed to stabilize the naphthalene anion, (b) EAa of −0.20 eV, in agreement with determinations by electron transmission spectroscopy, (c) energetics are consistent number waters required and (d) excess located on moiety Nph1−(H2O)n.
scitation.org
harvard.edu
jh.edu
aip.org参考文章(38)
Terence James Kemp, V. K. Milinchuk, V. I. Tupikov, Organic radiation chemistry handbook Ellis Horwood , Halsted Press. ,(1989)
C. Desfrançois, H. Abdoul‐Carime, J. P. Schermann, Electron attachment to isolated nucleic acid bases Journal of Chemical Physics. ,vol. 104, pp. 7792- 7794 ,(1996) , 10.1063/1.471484
S. S. Mitra, H. J. Bernstein, VIBRATIONAL SPECTRA OF NAPHTHALENE-d0, -α-d4, AND -d8 MOLECULES Canadian Journal of Chemistry. ,vol. 37, pp. 553- 562 ,(1959) , 10.1139/V59-076
J. C. M. Henning, 14N Hyperfine Structure in ESR Spectra of Heterocyclic Anions Journal of Chemical Physics. ,vol. 44, pp. 2139- 2155 ,(1966) , 10.1063/1.1726992
F. Stenman, Raman Scattering from Molecular Crystals. I. Powdered Naphthalene The Journal of Chemical Physics. ,vol. 54, pp. 4217- 4222 ,(1971) , 10.1063/1.1674661
H. Abdoul-Carime, A. Wakisaka, J. Flugge, H. Takeo, V. Periquet, J. P. Schermann, C. Desfrançois, Non-covalent binary interactions between some organic acids and bases Journal of the Chemical Society, Faraday Transactions. ,vol. 93, pp. 4289- 4293 ,(1997) , 10.1039/A704986B
G. J. Hoijtink, E. de Boer, P. H. van der Meij, W. P. Weijland, Reduction potentials of various aromatic hydrocarbons and their univalent anions Recueil des Travaux Chimiques des Pays-Bas. ,vol. 75, pp. 487- 503 ,(1956) , 10.1002/RECL.19560750502
Hahn Levanon, P. Neta, A.M. Trozzolo, Correlation of singlet energies of aromatic hydrocarbons with the rates of protonation of their anion radicals Chemical Physics Letters. ,vol. 54, pp. 181- 185 ,(1978) , 10.1016/0009-2614(78)85692-9
D. M. Neumark, K. R. Lykke, T. Andersen, W. C. Lineberger, Laser photodetachment measurement of the electron affinity of atomic oxygen. Physical Review A. ,vol. 32, pp. 1890- 1892 ,(1985) , 10.1103/PHYSREVA.32.1890
Gil Markovich, Stuart Pollack, Rina Giniger, Ori Cheshnovsky, Photoelectron spectroscopy of Cl−, Br−, and I− solvated in water clusters Journal of Chemical Physics. ,vol. 101, pp. 9344- 9353 ,(1994) , 10.1063/1.467965