Influence of Mg doping in magnetic properties of NiO nanoparticles and its electrical applications

作者: Bharathy Govindarajan , Raji Palanimuthu , K. M. Manikandan

DOI: 10.1007/S10854-019-00957-2

关键词:

摘要: Mg doped NiO nanoparticles MgxNi1−xO (x = 0, 0.1, 0.2, 0.3, 0.4) have been synthesized using sol–gel method. Their structure and morphology of the sample were analyzed X-ray diffractometer (XRD), transmission electron microscope (TEM) scanning (SEM) with energy dispersive spectrum (EDX). From XRD analysis, it is observed that can FCC a particle size 22 nm. Functional group analysis was carried out Fourier transform infrared spectroscopy (FTIR) Ultraviolet visible spectrometer. The obtained band gap 4.254 eV. Photoluminescence (PL) emission spectra showed blue strong at 345 nm. SEM TEM images confirmed spherical high crystalline nature samples. EDX purity magnetic properties samples vibrating magnetometer (VSM). 0.3 %Mg room temperature ferromagnetism higher saturation magnetization. used further for fabrication low cost counter electrode dye-sensitized solar cells (DSSCs). A thin film pure deposited on Fluorine tin oxide (FTO) coated glass substrate serves as an efficient plate to increase number holes induced electrocatalytic activity yield efficiency 2.4%.

参考文章(36)
Chuan Lin, Shaheen A Al-Muhtaseb, James A Ritter, None, Thermal Treatment of Sol-Gel Derived Nickel Oxide Xerogels Journal of Sol-Gel Science and Technology. ,vol. 28, pp. 133- 141 ,(2003) , 10.1023/A:1025653607374
Trang Vu Thi, Alok Kumar Rai, Jihyeon Gim, Jaekook Kim, High performance of Co-doped NiO nanoparticle anode material for rechargeable lithium ion batteries Journal of Power Sources. ,vol. 292, pp. 23- 30 ,(2015) , 10.1016/J.JPOWSOUR.2015.05.029
K. Anandan, V. Rajendran, Effects of Mn on the magnetic and optical properties and photocatalytic activities of NiO nanoparticles synthesized via the simple precipitation process Materials Science and Engineering B-advanced Functional Solid-state Materials. ,vol. 199, pp. 48- 56 ,(2015) , 10.1016/J.MSEB.2015.04.015
Marin Tadic, Dobrica Nikolic, Matjaz Panjan, Graeme R. Blake, Magnetic properties of NiO (nickel oxide) nanoparticles: Blocking temperature and Neel temperature Journal of Alloys and Compounds. ,vol. 647, pp. 1061- 1068 ,(2015) , 10.1016/J.JALLCOM.2015.06.027
Ghazaleh Allaedini, Payam Aminayi, Siti Masrinda Tasirin, Structural properties and optical characterization of flower-like Mg doped NiO AIP Advances. ,vol. 5, pp. 077161- ,(2015) , 10.1063/1.4927508
I Hotovy, J Huran, L Spiess, S Hascik, V Rehacek, Preparation of nickel oxide thin films for gas sensors applications Sensors and Actuators B-chemical. ,vol. 57, pp. 147- 152 ,(1999) , 10.1016/S0925-4005(99)00077-5
Li Li, Renjie Chen, Ge Jing, Guiyou Zhang, Feng Wu, Shi Chen, Improved performance of TiO2 electrodes coated with NiO by magnetron sputtering for dye-sensitized solar cells Applied Surface Science. ,vol. 256, pp. 4533- 4537 ,(2010) , 10.1016/J.APSUSC.2010.02.042
Brian O'Regan, Michael Grätzel, A low-cost, high-efficiency solar cell based on dye-sensitized colloidal TiO2 films Nature. ,vol. 353, pp. 737- 740 ,(1991) , 10.1038/353737A0
Marin Tadić, Matjaž Panjan, Dragana Marković, NiO/SiO2 nanostructure and the magnetic moment of NiO nanoparticles Materials Letters. ,vol. 64, pp. 2129- 2131 ,(2010) , 10.1016/J.MATLET.2010.07.006
Marin Tadic, Matjaz Panjan, Dragana Markovic, Boban Stanojevic, Djordje Jovanovic, Irena Milosevic, Vojislav Spasojevic, NiO core–shell nanostructure with ferromagnetic-like behavior at room temperature Journal of Alloys and Compounds. ,vol. 586, pp. S322- S325 ,(2014) , 10.1016/J.JALLCOM.2012.10.166