Magnetic blocking in a linear iron( I ) complex
作者： Joseph M. Zadrozny , Dianne J. Xiao , Mihail Atanasov , Gary J. Long , Fernande Grandjean
DOI: 10.1038/NCHEM.1630
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摘要: Mononuclear complexes of certain lanthanide ions are known to have large magnetization reversal barriers caused by strong spin–orbit coupling. Now, careful tuning the ligand field a transition metal complex has engendered comparable spin-reversal barrier — and in turn magnetic blocking at 4.5 K.
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