Integrated route to the L-aldohexoses using a common man-made chiral building block.
作者： Miwako Takeuchi , Takahiko Taniguchi , Kunio Ogasawara
DOI: 10.1002/(SICI)1520-636X(2000)12:5/6<338::AID-CHIR6>3.0.CO;2-Y
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摘要: Starting from a common man-made chiral sugar building block, five out of eight L-aldohexoses have been synthesized in diastereocontrolled manner to complete an integrated synthesis the possible aldohexoses; remaining three L-hexoses were same block. Thus, L-altrose, L-mannose, L-allose, L-talose, and L-glucose obtained present investigation on basis inherent convex-face selectivity exerted by Chirality 12:338–341, 2000. © 2000 Wiley-Liss, Inc.
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