A Practical Synthesis of Tetrachloroethylene Oxide
作者： R. W. Campbell , O. Vogl
DOI: 10.1080/00222337708061286
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摘要: Abstract Tetrachloroethylene oxide has been synthesized by direct oxidation of tetrachloroethylene with oxygen in the presence ultraviolet light. This preparation resulted a mixture and trichloroacetyl chloride approximately equal amounts under most favorable conditions. rearranges readily to above 60 C an activation energy E 3.0 × 104 cal/mole pre-exponential factor A 1.9 1013. All attempts polymerize variety conditions failed.
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