Influence of anions on the kinetics of zeolite A crystallization:: a population balance analysis

作者: Sanja Bosnar , Tatjana Antonić-Jelić , Josip Bronić , Ivan Krznarić , Boris Subotić

DOI: 10.1016/J.JCRYSGRO.2004.03.040

关键词:

摘要: Abstract Kinetics of nucleation, crystal growth and entire process crystallization zeolite A in the presence different sodium salts were analyzed by population balance method. Both rate increase with increasing concentration sulfate dissolved liquid phase crystallizing system, but equimolar amounts (with respect to Na + ions) influences only on extent which can be attributed experimental errors characteristic for this type experiments. Thus, it was concluded that ions not associated anions influence A. Insensibility particulate properties crystalline end products supports conclusion explained “memory”effect specially prepared amorphous aluminosilicate gel precursors.

参考文章(23)
B. Subotič, N. Mašič, I. Šmit, Analysis of Particulate Processes During the Transformation of Zeolite A into Hydroxysodalite Studies in Surface Science and Catalysis. ,vol. 24, pp. 207- 214 ,(1985) , 10.1016/S0167-2991(08)65285-4
S Bosnar, B Subotic, Mechanism and kinetics of the growth of zeolite microcrystals Microporous and Mesoporous Materials. ,vol. 28, pp. 483- 493 ,(1999) , 10.1016/S1387-1811(98)00338-2
Molecular Sieve Zeolites-II AMERICAN CHEMICAL SOCIETY. ,(1971) , 10.1021/BA-1971-0101
Richard Maling Barrer, Hydrothermal Chemistry of Zeolites ,(1982)
B. Subotić, L. Sekovanić, Transformation of zeolite A into hydroxysodalite Journal of Crystal Growth. ,vol. 75, pp. 561- 572 ,(1986) , 10.1016/0022-0248(86)90102-8
Boris Subotić, Tatjana Antonić, Sanja Bosnar, Josip Bronić, Mirjana Škreblin, Analysis of the distribution of nuclei in matrices of differently prepared and treated aluminosilicate gels Studies in Surface Science and Catalysis. ,vol. 125, pp. 157- 164 ,(1999) , 10.1016/S0167-2991(99)80209-2
B. Subotić, D. Škrtić, I. Šmit, L. Sekovanić, Transformation of zeolite A into hydroxysodalite Journal of Crystal Growth. ,vol. 50, pp. 498- 508 ,(1980) , 10.1016/0022-0248(80)90099-8