Supported N-heterocyclic carbene complexes in catalysis
作者： William J. Sommer , Marcus Weck
DOI: 10.1016/J.CCR.2006.07.004
关键词:
摘要: N-Heterocyclic carbenes (NHCs) have been known to be outstanding ligands for a variety of organometallic complexes that are key components in catalysis. For the past 10 years, interest has grown towards tethered versions this type onto supports including polymers and silica. In report, we review current approaches supported NHC-based catalysts. particular, olefin metathesis catalysts palladium coupling chemistries described. While first NHC reported less than years ago, blossoming area increased exponentially since then offers interesting perspectives future
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Jürgen Schwarz, Volker P. W. Böhm, Michael G. Gardiner, Manja Grosche, Wolfgang A. Herrmann, Wolfgang Hieringer, Gabriele Raudaschl-Sieber, Polymer‐Supported Carbene Complexes of Palladium: Well‐Defined, Air‐Stable, Recyclable Catalysts for the Heck Reaction Chemistry: A European Journal. ,vol. 6, pp. 1773- 1780 ,(2000) , 10.1002/(SICI)1521-3765(20000515)6:10<1773::AID-CHEM1773>3.0.CO;2-P
Wolfgang A. Herrmann, Claus-Peter Reisinger, Michael Spiegler, Chelating N-heterocyclic carbene ligands in palladium-catalyzed heck-type reactions Journal of Organometallic Chemistry. ,vol. 557, pp. 93- 96 ,(1998) , 10.1016/S0022-328X(97)00736-5
Jinkun Huang, Laleh Jafarpour, Anna C. Hillier, Edwin D. Stevens, Steven P. Nolan, Structural and Thermochemical Studies of Chiral Nucleophilic Carbenes in the Cp*RuCl(L*) (Cp* = η5-C5Me5; L* = Chiral Nucleophilic Carbene) System Organometallics. ,vol. 20, pp. 2878- 2882 ,(2001) , 10.1021/OM010137D
Stephen J Connon, Siegfried Blechert, A solid-supported phosphine-free ruthenium alkylidene for olefin metathesis in methanol and water. Bioorganic & Medicinal Chemistry Letters. ,vol. 12, pp. 1873- 1876 ,(2002) , 10.1016/S0960-894X(02)00260-3
Michael R. Buchmeiser, Recent advances in the synthesis of supported metathesis catalysts New Journal of Chemistry. ,vol. 28, pp. 549- 557 ,(2004) , 10.1039/B315236G
M. Tobias Zarka, Martin Bortenschlager, Klaus Wurst, Oskar Nuyken, Ralf Weberskirch, Immobilization of a Rhodium Carbene Complex to an Amphiphilic Block Copolymer for Hydroformylation of 1-Octene under Aqueous Two-Phase Conditions Organometallics. ,vol. 23, pp. 4817- 4820 ,(2004) , 10.1021/OM049495H
Dirk Fischer, Siegfried Blechert, Highly active silica gel-supported metathesis (Pre)catalysts Advanced Synthesis & Catalysis. ,vol. 347, pp. 1329- 1332 ,(2005) , 10.1002/ADSC.200505106
O. J. Scherer, G. Schieder, N,P‐Organometalated Phosphine Imines from Aminophosphines Angewandte Chemie. ,vol. 7, pp. 75- 76 ,(1968) , 10.1002/ANIE.196800751
Ai-E Wang, Jun Zhong, Jian-Hua Xie, Kai Li, Qi-Lin Zhou, Highly Efficient Suzuki Cross‐Coupling Catalyzed by Palladium/Phosphine‐Imidazolium Carbene System Advanced Synthesis & Catalysis. ,vol. 346, pp. 595- 598 ,(2004) , 10.1002/ADSC.200404015
Monika Mayr, Michael R. Buchmeiser, Klaus Wurst, Synthesis of a Silica‐Based Heterogeneous Second Generation Grubbs Catalyst Advanced Synthesis & Catalysis. ,vol. 344, pp. 712- 719 ,(2002) , 10.1002/1615-4169(200208)344:6/7<712::AID-ADSC712>3.0.CO;2-W