Fluorescent behaviour in host–guest interactions. Part 3. Fluorescent sensing for organic guests using three types of amino-β-cyclodextrins
作者： Yasushi Takenaka , Miwako Higashi , Noboru Yoshida
DOI: 10.1039/B108204N
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摘要: The pH- and temperature-dependent fluorescence behaviour in aqueous solution of three amino-β-cyclodextrins (amino-β-CDx), 1, 2 3, bearing an amide-linked naphthalene probe has been investigated. emission intensity at λmax(em) 1 decreased dramatically with increasing temperature. pH-dependent spectrum was also recorded. Operation the in–out equilibrium mainly analyzed using 1H NMR circular dichroism spectra. application to organic-guest sensing is demonstrated by several examples. These findings suggest that new host molecule, will be excellent CDx-based fluorescent sensor for temperature, pH neutral organic guests.
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sci-hub.se 参考文章(21)
Roberto Corradini, Arnaldo Dossena, Gianni Galaverna, Rosangela Marchelli, Anna Panagia, Giorgio Sartor, Fluorescent Chemosensor for Organic Guests and Copper(II) Ion Based on Dansyldiethylenetriamine-Modified β-Cyclodextrin Journal of Organic Chemistry. ,vol. 62, pp. 6283- 6289 ,(1997) , 10.1021/JO970349D
Sally Anderson, Tim D. W. Claridge, Harry L. Anderson, Azo‐Dye Rotaxanes Angewandte Chemie. ,vol. 36, pp. 1310- 1313 ,(1997) , 10.1002/ANIE.199713101
Norbert Schaschke, Stella Fiori, Elisabeth Weyher, Chantal Escrieut, Daniel Fourmy, Gerhard Müller, Luis Moroder, Cyclodextrin as Carrier of Peptide Hormones. Conformational and Biological Properties of β-Cyclodextrin/Gastrin Constructs Journal of the American Chemical Society. ,vol. 120, pp. 7030- 7038 ,(1998) , 10.1021/JA973852G
Akihiko. Ueno, Iwao. Suzuki, Tetsuo. Osa, Host-guest sensory systems for detecting organic compounds by pyrene excimer fluorescence Analytical Chemistry. ,vol. 62, pp. 2461- 2466 ,(1990) , 10.1021/AC00221A010
Noboru. Yoshida, Akitoshi. Seiyama, Masatoshi. Fujimoto, Dynamic aspects in host-guest interactions: Mechanism for molecular recognition by .alpha.-cyclodextrin of alkyl-substituted hydroxyphenylazo derivatives of sulfanilic acid The Journal of Physical Chemistry. ,vol. 94, pp. 4246- 4253 ,(1990) , 10.1021/J100373A068
Mark A. Mortellaro, Wanda K. Hartmann, Daniel G. Nocera, Regioisomeric Effects on the Excited State Processes of a Cyclodextrin Modified with a Lumophore Angewandte Chemie. ,vol. 35, pp. 1945- 1946 ,(1996) , 10.1002/ANIE.199619451
Shelli R. McAlpine, Miguel A. Garcia-Garibay, Inside−Outside Isomerism of β-Cyclodextrin Covalently Linked with a Naphthyl Group Journal of the American Chemical Society. ,vol. 118, pp. 2750- 2751 ,(1996) , 10.1021/JA953061J
Anne Hersey, Brian H. Robinson, Thermodynamic and kinetic study of the binding of azo-dyes to α-cyclodextrin Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases. ,vol. 80, pp. 2039- 2052 ,(1984) , 10.1039/F19848002039
Noboru Yoshida, Yuji Fujita, Dynamic Aspects in Host-Guest Interactions. 3. Kinetics and Mechanism of Molecular Recognition by Hexakis(2,6-di-O-methyl)-.alpha.-cyclodextrin of Some Azo Guest Molecules The Journal of Physical Chemistry. ,vol. 99, pp. 3671- 3677 ,(1995) , 10.1021/J100011A039
Alexey V. Eliseev, Hans-Joerg Schneider, Molecular Recognition of Nucleotides, Nucleosides, and Sugars by Aminocyclodextrins Journal of the American Chemical Society. ,vol. 116, pp. 6081- 6088 ,(1994) , 10.1021/JA00093A004