The Scattering of Atoms from Diatomic Molecules

作者: Charles F. Curtiss , F. T. Adler

DOI: 10.1063/1.1700387

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摘要: The quantum mechanics of the collision an atom with a diatomic molecule is discussed. This example scattering particles by nonspherical potential field. In region in which and are not interacting, wave function for system can be written as product free that molecule. By analysis this one write asymptotic form true terms coefficients, representing angular dependence transition probabilities. previous paper, group theoretical arguments were used to separate rotational coordinates from n‐particle Schroedinger equation. A set coupled differential equations internal functions was derived. present coefficients obtained solutions involving three specifying configuration. equation...

参考文章(4)
G. H. Shortley, The Theory of Atomic Spectra ,(1935)
C. F. Curtiss, J. O. Hirschfelder, F. T. Adler, The Separation of the Rotational Coordinates from the N‐Particle Schroedinger Equation The Journal of Chemical Physics. ,vol. 18, pp. 1638- 1642 ,(1950) , 10.1063/1.1747553
J. O. Hirschfelder, E. Wigner, Separation of Rotational Coördinates from the Schrödinger Equation for N Particles. Proceedings of the National Academy of Sciences of the United States of America. ,vol. 21, pp. 113- 119 ,(1935) , 10.1073/PNAS.21.2.113