Hetero-complexed dual tridendate ruthenium complex, and preparation method of dye-sensitized solar cell

作者: 吴冠霖 , 周俊诚 , 季昀

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摘要: A hybrid ligands, tridentate bis ruthenium complex comprising a chemical formula represented by the (1): RuL1L2 ...... (1), Ru is ruthenium, L1, and L2 heterocyclic group ligand. Group wherein R1-R3 selected from hydrogen, carboxylic acid group, salts of sulfonic salt phosphoric consisting of: L1 has structure (2) . The G1G2G3 (3) where to (7) Gl G3 (4) of, G2 formulas (8): having : substituents R 'and "is halo, cyano (cyano, CN), trifluoromethanesulfonyl (trifluoromethyl, CF3), C2-C10 fluorinated alkyl amino (amino), C1-C10 alkyl, alkenyl, alkynyl, C3-C20 cycloalkyl, cycloalkenyl, C1-C20 heterocycloalkyl, heterocycloalkenyl, aryl, heteroaryl group. dye sensitizer aforementioned complexes can be used as dye-sensitized solar cell was prepared.

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