Facilitated proton transfer across liquid | liquid interfaces under forced hydrodynamic conditions. Determination of partition coefficients of neutral weak bases
作者： F. Vega Mercado , J.M. Ovejero , F.M. Zanotto , M.R. Serial , M.I. Velasco
DOI: 10.1016/J.JELECHEM.2017.03.005
关键词:
摘要: Abstract A novel quantitative methodology to determine the partition coefficients of neutral weak bases is developed. This new electrochemical approach based on measurement total transferred charge across oil | water interface under forced hydrodynamic conditions. The complete procedure has been validated by computational simulations and experimental results (Tylosin A). In addition, flow pattern caused inside cell was simulated with fluid dynamics using finite element methods correlated obtained magnetic resonance imaging.
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