UV emitting Pb2+ doped SrZrO3 phosphors prepared by sol-gel procedure
作者： N. Singh , Sumandeep Kaur , M. Jayasimhadri , M.S. Pathak , S. Watanabe
DOI: 10.1016/J.CERAMINT.2018.06.153
关键词:
摘要: Abstract A series of Pb2+-doped SrZrO3 phosphors with a varying Pb2+ concentration has been successfully synthesized using the sol-gel method. The structural, morphological, and luminescence properties along electron paramagnetic resonance (EPR) have investigated in details. structural analysis was carried out by recording X-ray diffraction (XRD) patterns, which confirms pure-phase formation phosphors. morphological study performed scanning microscope (SEM) that showed micron-sized particles irregular morphologies. photoluminescence excitation emission spectra were also recorded. intensity shows maximum at 360 nm pumped 278 nm for SrZrO3:Pb2+. optimized is 0.015 mol. Investigations un-doped doped phosphor technique. Pure exhibits an axially symmetric EPR line g || = 1.93 ⊥ = 1.99. These lines are ascribed to Zr3+ ion. Additional not observed
sci-hub.se 参考文章(24)
Sandra Wright, R. C. Barklie, Electron paramagnetic resonance characterization of defects in monoclinic HfO2 and ZrO2 powders Journal of Applied Physics. ,vol. 106, pp. 103917- ,(2009) , 10.1063/1.3259405
Yun-Chen Wu, De-Yin Wang, Teng-Ming Chen, Chi-Shen Lee, Kuo-Ju Chen, Hao-chung Kuo, A Novel Tunable Green- to Yellow-Emitting β-YFS:Ce3+ Phosphor for Solid-State Lighting ACS Applied Materials & Interfaces. ,vol. 3, pp. 3195- 3199 ,(2011) , 10.1021/AM2006965
Sülin Taşcıoğlu, İlhan Pekgözlü, Ayhan Mergen, Synthesis and photoluminescence properties of Pb2+ doped SrAl2B2O7 Materials Chemistry and Physics. ,vol. 112, pp. 78- 82 ,(2008) , 10.1016/J.MATCHEMPHYS.2008.05.031
Maja Orłowska, Andrzej M. Kłonkowski, Julia Jezierska, Jacek Ryl, Luminescence recognition material as an INHIBIT logic gate in presence of Pb2+ and Cu2+ ions in aqueous solutions Sensors and Actuators B-chemical. ,vol. 186, pp. 396- 406 ,(2013) , 10.1016/J.SNB.2013.06.010
Jean-Marc Costantini, François Beuneu, Sarah Morrison-Smith, Ram Devanathan, William J. Weber, Paramagnetic defects in electron-irradiated yttria-stabilized zirconia: Effect of yttria content Journal of Applied Physics. ,vol. 110, pp. 123506- ,(2011) , 10.1063/1.3666062
R. D. Shannon, C. T. Prewitt, Effective ionic radii in oxides and fluorides Acta Crystallographica Section B Structural Crystallography and Crystal Chemistry. ,vol. 25, pp. 925- 946 ,(1969) , 10.1107/S0567740869003220
H. F. Folkerts, G. Blasse, Luminescence of Pb2+ in several calcium borates Journal of Materials Chemistry. ,vol. 5, pp. 273- 276 ,(1995) , 10.1039/JM9950500273
D. S. Thakare, S. K. Omanwar, P. L. Muthal, S. M. Dhopte, V. K. Kondawar, S. V. Moharil, UV-emitting phosphors: synthesis, photoluminescence and applications physica status solidi (a). ,vol. 201, pp. 574- 581 ,(2004) , 10.1002/PSSA.200306720
Bruno Boizot, Guillaume Petite, Dominique Ghaleb, Georges Calas, Radiation induced paramagnetic centres in nuclear glasses by EPR spectroscopy Nuclear Instruments & Methods in Physics Research Section B-beam Interactions With Materials and Atoms. ,vol. 141, pp. 580- 584 ,(1998) , 10.1016/S0168-583X(98)00102-5
Veda Ramaswamy, Bhavana Tripathi, D Srinivas, A.V Ramaswamy, Ricardo Cattaneo, Roel Prins, Structure and Redox Behavior of Zirconium in Microporous Zr-Silicalites Studied by EXAFS and ESR Techniques Journal of Catalysis. ,vol. 200, pp. 250- 258 ,(2001) , 10.1006/JCAT.2001.3213