On the role of water, temperature, and glass transition in the corrosion protection behavior of epoxy coatings for underground pipelines

作者: Hung M. Ha , Akram Alfantazi

DOI: 10.1007/S11998-015-9705-0

关键词:

摘要: Water transport kinetics in the coatings were markedly enhanced and coating impedances decreased exponentially as temperature increased. The effect of on impedance was attributed to change defect area fraction caused by thermal expansion polymers. dependence reversible a non-aqueous environment but irreversible an aqueous environment. This is plasticization water polymer chains. glass transition during short period exposure heat source insignificant.

参考文章(51)
Gregory B. McKenna, Glass Formation and Glassy Behavior Comprehensive Polymer Science and Supplements. ,vol. 10, pp. 311- 362 ,(1989) , 10.1016/B978-0-08-096701-1.00047-1
M. Bešter-Rogač, R. Neueder, J. Barthel, Conductivity of Sodium Chloride in Water + 1,4-Dioxane Mixtures from 5 to 35°C II. Concentrated Solution Journal of Solution Chemistry. ,vol. 29, pp. 51- 61 ,(2000) , 10.1023/A:1005114500861
Guido Grundmeier, Alda Simões, Corrosion Protection by Organic Coatings Encyclopedia of Electrochemistry. ,(2003) , 10.1002/9783527610426.BARD040504
John Crank, The mathematics of diffusion ,(1956)
Hartmut Ochs, Jörg Vogelsang, Effect of temperature cycles on impedance spectra of barrier coatings under immersion conditions Electrochimica Acta. ,vol. 49, pp. 2973- 2980 ,(2004) , 10.1016/J.ELECTACTA.2004.01.056
N.L. Thomas, The barrier properties of paint coatings Progress in Organic Coatings. ,vol. 19, pp. 101- 121 ,(1991) , 10.1016/0033-0655(91)80001-Y