Dealkylation and Rearrangement Kinetics of 2-Isopropylphenol in Supercritical Water

作者: Takafumi Sato , Gaku Sekiguchi , Motofumi Saisu , Masaru Watanabe , Tadafumi Adschiri

DOI: 10.1021/IE010763A

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摘要: The decomposition of 2-isopropylphenol at temperatures 613−713 K and water densities 0−0.6 g/cm3 yielded phenol, propene, 2-propylphenol. was determined to occur via two reaction pathways:  (1) dealkylation produce phenol propene (2) rearrangement the propyl functional group from rate constant for increased proportionally with increasing density. invariant constants could be correlated as a function temperature density global model.

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