Electrodeposited Ni–Cr2O3 nanocomposite anodes for ethanol electrooxidation
作者： H.B. Hassan , Z. Abdel Hamid
DOI: 10.1016/J.IJHYDENE.2011.01.024
关键词:
摘要: Abstract Nanocomposite coatings of Ni–Cr 2 O 3 supported on carbon electrodes have been prepared by electrodeposition technique from nickel Watts bath in presence Cr nanoparticles. Their electrochemical catalytic activities evaluated towards electrooxidation ethanol 1.0 M NaOH solution using cyclic voltammetry, chronoamperometry and Tafel plots. The performance the anodes as a function co-deposited content was studied. activity fabricated increases with increasing volume fraction percent (V f %) deposited film up to 7V %. /C (7V electrode displayed significantly enhanced stability compared Ni/C electrode. kinetic parameters Ni(OH) /NiOOH oxidation at evaluated.
elsevier.com
sci-hub.se 参考文章(53)
M.-C. Morin, C. Lamy, J.-M. Léger, J.-L. Vasquez, A. Aldaz, Structural effects in electrocatalysis Journal of Electroanalytical Chemistry and Interfacial Electrochemistry. ,vol. 283, pp. 287- 302 ,(1990) , 10.1016/0022-0728(90)87396-2
J. Fransaer, J. P. Celis, J. R. Roos, Analysis of the Electrolytic Codeposition of Non‐Brownian Particles with Metals Journal of The Electrochemical Society. ,vol. 139, pp. 413- 425 ,(1992) , 10.1149/1.2069233
M.A. Abdel Rahim, Hanaa B. Hassan, R.M. Abdel Hamid, A systematic study on the effect of OH− and Ni2+ ions on the electro-catalytic oxidation of methanol at Ni-S-1 electrode Journal of Power Sources. ,vol. 154, pp. 59- 65 ,(2006) , 10.1016/J.JPOWSOUR.2005.03.198
H. Heli, A. Jabbari, M. Zarghan, A.A. Moosavi-Movahedi, Copper nanoparticles–carbon microparticles nanocomposite for electrooxidation and sensitive detection of sotalol Sensors and Actuators B-chemical. ,vol. 140, pp. 245- 251 ,(2009) , 10.1016/J.SNB.2009.04.021
Junchao Huang, Zhaolin Liu, Chaobin He, Leong Ming Gan, Synthesis of PtRu nanoparticles from the hydrosilylation reaction and application as catalyst for direct methanol fuel cell Journal of Physical Chemistry B. ,vol. 109, pp. 16644- 16649 ,(2005) , 10.1021/JP052667J
M. Vuković, Voltammetry and anodic stability of a hydrous oxide film on a nickel electrode in alkaline solution Journal of Applied Electrochemistry. ,vol. 24, pp. 878- 882 ,(1994) , 10.1007/BF00348775
Yu Ding, Ying Wang, Liang Su, Michael Bellagamba, Heng Zhang, Yu Lei, Electrospun Co3O4 nanofibers for sensitive and selective glucose detection Biosensors and Bioelectronics. ,vol. 26, pp. 542- 548 ,(2010) , 10.1016/J.BIOS.2010.07.050
Ruidong Xu, Junli Wang, Lifang He, Zhongcheng Guo, None, Study on the characteristics of Ni–W–P composite coatings containing nano-SiO2 and nano-CeO2 particles Surface & Coatings Technology. ,vol. 202, pp. 1574- 1579 ,(2008) , 10.1016/J.SURFCOAT.2007.07.012
T. Maiyalagan, Keith Scott, Performance of carbon nanofiber supported Pd-Ni catalysts for electro-oxidation of ethanol in alkaline medium Journal of Power Sources. ,vol. 195, pp. 5246- 5251 ,(2010) , 10.1016/J.JPOWSOUR.2010.03.022
H. Heli, H. Yadegari, Nanoflakes of the cobaltous oxide, CoO: Synthesis and characterization Electrochimica Acta. ,vol. 55, pp. 2139- 2148 ,(2010) , 10.1016/J.ELECTACTA.2009.11.047