Structural Investigations of Oligomeric Axially Bridged Ruthenium Phthalocyanines by EXAFS Spectroscopy
作者： Achim Weber , Teja S. Ertel , Ulrich Reinöhl , Martin Feth , Helmut Bertagnolli
DOI: 10.1002/1099-0682(200103)2001:3<679::AID-EJIC679>3.0.CO;2-3
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摘要: To obtain more information about the structure of phthalocyaninatoruthenium compounds an EXAFS investigation was carried out on amorphous bisaxially bridged phthalocyaninatoruthenium(II) oligomers, [PcRu(tz)]n (1), [PcRu(pyz)]n (2) and [PcRu(dib)]n (3). Detailed structural models for three were deduced from determined atomic distances around metal center. A bisaxial ligands could be proven all additionally, parameters determined.
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