Charge-compensation effects and their influence on spectroscopic properties of alkali halides doped with ions; the case of a NaBr host

作者: K Hermanowicz

DOI: 10.1088/0953-8984/9/6/020

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摘要: The Raman scattering, vibrational, electron spin-resonance, and luminescence spectra of the ion in a sodium bromide crystal host are reported. results indicate that complex is trapped two nonequivalent symmetries, which have been identified characterized by parameters D spin Hamiltonian B field. IR discussed on basis possible symmetries ion. Following vibrational analysis vibronic assignment phosphorescence spectrum proposed. role influence charge-compensational configurations as regards spectroscopic properties chromium (III) analysed.

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