Novel erbium(III) complexes with 2,6-dimethyl-3,5-heptanedione and different N,N-donor ligands for ormosil and PMMA matrices doping
作者： P Martín-Ramos , V Lavín , M Ramos Silva , IR Martín , F Lahoz
DOI: 10.1039/C3TC30686K
关键词:
摘要: Three novel complexes, [Er(dmh)3(bipy)], [Er(dmh)3bath] and [Er(dmh)3(5NO2phen)], with 2,6-dimethyl-3,5-heptanedione (Hdmh) as the main sensitizer either 2,2′-bipyridine (bipy), bathophenanthroline (bath) or 5-nitro-1,10-phenanthroline (5NO2phen) synergistic ligands were synthesized. Upon excitation at maximum absorption of ligands, complexes show characteristic near-infrared (NIR) luminescence Er3+ ions, due to efficient energy transfer from central ion via antenna effect. Single crystals grown their structures determined showing different Er–N distances. The compound shorter distances, was found be best light harvester for transferring lanthanide among three studied compounds. Finally, have been assessed application in sol–gel polymer-based waveguides optical amplifiers through inclusion into ormosil polymethylmethacrylate matrices. dispersion successful bipy 5NO2phen cases, properties hybrid materials mimicking those pure complexes.
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sci-hub.se 参考文章(27)
L‐N Sun, H‐J Zhang, L‐S Fu, F‐Y Liu, Q‐G Meng, C‐Y Peng, J‐B Yu, None, A New Sol–Gel Material Doped with an Erbium Complex and Its Potential Optical‐Amplification Application Advanced Functional Materials. ,vol. 15, pp. 1041- 1048 ,(2005) , 10.1002/ADFM.200400386
L. Armelao, S. Quici, F. Barigelletti, G. Accorsi, G. Bottaro, M. Cavazzini, E. Tondello, Design of luminescent lanthanide complexes: From molecules to highly efficient photo-emitting materials Coordination Chemistry Reviews. ,vol. 254, pp. 487- 505 ,(2010) , 10.1016/J.CCR.2009.07.025
R.A.S. Ferreira, P.S. André, L.D. Carlos, Organic–inorganic hybrid materials towards passive and active architectures for the next generation of optical networks Optical Materials. ,vol. 32, pp. 1397- 1409 ,(2010) , 10.1016/J.OPTMAT.2010.06.019
Glen B. Deacon, David J. Evans, Peter C. Junk, New Variations on the LnCl3(L)n (L = tetrahydrofuran or 1, 2-dimethoxyethane) Structural Theme — NdCl3(dme)2 and YbCl3(thf)3.5 Zeitschrift für anorganische und allgemeine Chemie. ,vol. 628, pp. 2033- 2036 ,(2002) , 10.1002/1521-3749(200209)628:9/10<2033::AID-ZAAC2033>3.0.CO;2-G
W. Strek, J. Sokolnicki, J. Legendziewicz, K. Maruszewski, R. Reisfeld, T. Pavich, Optical properties of Eu(III) chelates trapped in silica gel glasses Optical Materials. ,vol. 13, pp. 41- 48 ,(1999) , 10.1016/S0925-3467(99)00009-9
Zhefeng Li, Jiangbo Yu, Liang Zhou, Hongjie Zhang, Ruiping Deng, Zhiyong Guo, 1.54 μm Near-infrared photoluminescent and electroluminescent properties of a new Erbium (III) organic complex Organic Electronics. ,vol. 9, pp. 487- 494 ,(2008) , 10.1016/J.ORGEL.2008.02.010
Li-juan Bian, Hong-an Xi, Xue-feng Qian, Jie Yin, Zi-kang Zhu, Qing-hua Lu, Synthesis and luminescence property of rare earth complex nanoparticles dispersed within pores of modified mesoporous silica Materials Research Bulletin. ,vol. 37, pp. 2293- 2301 ,(2002) , 10.1016/S0025-5408(02)00934-0
Renata Reisfeld, Tsiala Saraidarov, Marek Pietraszkiewicz, Stefan Lis, Luminescence of europium(III) compounds in zirconia xerogels Chemical Physics Letters. ,vol. 349, pp. 266- 270 ,(2001) , 10.1016/S0009-2614(01)01215-5
F. Meinardi, N. Colombi, S. Destri, W. Porzio, S. Blumstengel, M. Cerminara, R. Tubino, Novel erbium complexes with low band-gap for infrared laser and optical amplifiers Synthetic Metals. ,vol. 137, pp. 959- 960 ,(2003) , 10.1016/S0379-6779(02)00948-7
Philip Lenaerts, Annick Storms, Jules Mullens, Jan D'Haen, Christiane Görller-Walrand, Koen Binnemans, Kris Driesen, Thin Films of Highly Luminescent Lanthanide Complexes Covalently Linked to an Organic−Inorganic Hybrid Material via 2-Substituted Imidazo[4,5-f]-1,10-phenanthroline Groups Chemistry of Materials. ,vol. 17, pp. 5194- 5201 ,(2005) , 10.1021/CM051133S