Metal-carbon multiple bonded complexes Carbene, vinylidene and allenylidene complexes of ruthenium and osmium supported by macrocyclic ligands
作者： C CHE , C HO , J HUANG
DOI: 10.1016/J.CCR.2007.03.019
关键词:
摘要: Abstract In this review, we present our recent studies on the synthesis, structures, spectroscopic and electrochemical properties, reactivities of ruthenium/osmium–carbon multiple bonded complexes. The first part review deals with chemistry ruthenium/osmium porphyrin carbene complexes related metal (including iron ruthenium supported by salens or polypyridines). second describes vinylidene allenylidene macrocyclic tertiary amine ligands Me3tacn (1,4,7-trimethyl-1,4,7-triazacyclononane) 16-TMC (1,5,9,13-tetramethyl-1,5,9,13-tetraaza-cyclohexadecane).
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