Fluids Confined in Porous Materials: Towards a Unified Understanding of Thermodynamics and Dynamics
作者： Peter A. Monson
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摘要: A recently developed theoretical approach to understand the relaxation processes for fluids confined in mesoporous materials, especially adsorption/desorption from bulk gases, is discussed. The theory based on a lattice gas formulation of molecular interactions system and referred as dynamic mean field theory. has important property that limiting behavior at long times consistent with results (or density functional theory) model. In this sense it provides unified picture thermodynamics dynamics system. Two illustrative applications are presented. first capillary condensation finite length slit pore contact gas. second application cavitation during desorption an inkbottle outlook future developments also
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