Efficient copper(i)-catalyzed oxidative intermolecular 1,2-estersulfenylation of styrenes with peroxyesters and disulfides.
作者： Yiting Luo , Rongkui Su , Hongming Yang
DOI: 10.1039/D0OB00823K
关键词:
摘要: A simple and practical method for the synthesis of thio-substituted esters through copper(I)-catalyzed intermolecular 1,2-estersulfenylation styrenes with peroxyesters disulfides was developed. In this transformation, two new C–S bond C–O were constructed simultaneously under a copper catalyst system, transformation exhibits broad substrate scope good functional group compatibility. addition, can also be applied to arylthiols. It should noted that not only acted as nucleophilic reagents but oxidants.
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