A nanosized Mn oxide/boron nitride composite as a catalyst for water oxidation
作者： Mohammad Mahdi Najafpour , Sepideh Madadkhani , Tatsuya Tomo , Suleyman I. Allakhverdiev
DOI: 10.1039/C7NJ00049A
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摘要: Herein, a nanosized Mn oxide/boron nitride composite is reported as catalyst for water oxidation. This study interesting because boron one of the most stable and inert compounds can form new with oxides. The was synthesized using straightforward simple procedure characterized, showing that supported Mn(III,IV) oxide on nitride. water-oxidizing activity studied in presence cerium(IV) ammonium nitrate photoproduced Ru(bpy)33+ oxidants. optimized calcined at 200–300 °C showed turnover frequency 0.15 (mmolO2/s−1 molMn−1) nitrate.
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Mohammad Mahdi Najafpour, Mohadeseh Zarei Ghobadi, Bahram Sarvi, Behzad Haghighi, An engineered polypeptide around nano-sized manganese–calcium oxide: copying plants for water oxidation Dalton Transactions. ,vol. 44, pp. 15271- 15278 ,(2015) , 10.1039/C5DT01443C
Mohammad Mahdi Najafpour, Emad Amini, Nano-sized Mn oxides on halloysite or high surface area montmorillonite as efficient catalysts for water oxidation with cerium(IV) ammonium nitrate: support from natural sources Dalton Transactions. ,vol. 44, pp. 15441- 15449 ,(2015) , 10.1039/C5DT02336J
Kazuo Nakamoto, Infrared and Raman Spectra of Inorganic and Coordination Compounds ,(1978)
Xinjun Wang, Yi Xie, Qixun Guo, Synthesis of high quality inorganic fullerene-like BN hollow spheres via a simple chemical route Chemical Communications. pp. 2688- 2689 ,(2003) , 10.1039/B308264D
M. Wiechen, M. M. Najafpour, S. I. Allakhverdiev, L. Spiccia, Water oxidation catalysis by manganese oxides: learning from evolution Energy and Environmental Science. ,vol. 7, pp. 2203- 2212 ,(2014) , 10.1039/C4EE00681J
J. E. Post, Manganese oxide minerals: Crystal structures and economic and environmental significance Proceedings of the National Academy of Sciences of the United States of America. ,vol. 96, pp. 3447- 3454 ,(1999) , 10.1073/PNAS.96.7.3447
Mohammad Mahdi Najafpour, Małgorzata Hołyńska, Saeideh Salimi, Applications of the “nano to bulk” Mn oxides: Mn oxide as a Swiss army knife Coordination Chemistry Reviews. ,vol. 285, pp. 65- 75 ,(2015) , 10.1016/J.CCR.2014.11.001
Zhixi Bian, Ali Shakouri, Bin Liu, High-power limitation of passive ring-resonator-coupled lasers in the presence of material nonlinearity Journal of Applied Physics. ,vol. 95, pp. 3816- 3818 ,(2004) , 10.1063/1.1655675
Mohammad Mahdi Najafpour, Atefeh Nemati Moghaddam, Young Nam Yang, Eva-Mari Aro, Robert Carpentier, Julian J. Eaton-Rye, Choon-Hwan Lee, Suleyman I. Allakhverdiev, Biological water-oxidizing complex: a nano-sized manganese–calcium oxide in a protein environment Photosynthesis Research. ,vol. 114, pp. 1- 13 ,(2012) , 10.1007/S11120-012-9778-X
Mohammad Mahdi Najafpour, Mahnaz Abasi, Tatsuya Tomo, Suleyman I. Allakhverdiev, Nanolayered manganese oxide/C60 composite: a good water-oxidizing catalyst for artificial photosynthetic systems† Dalton Transactions. ,vol. 43, pp. 12058- 12064 ,(2014) , 10.1039/C4DT00599F