A new metal-organic framework with high stability based on zirconium for sensing small molecules
作者： Wenjuan Zhang , Hongliang Huang , Dahuan Liu , Qingyuan Yang , Yuanlong Xiao
DOI: 10.1016/J.MICROMESO.2013.01.003
关键词:
摘要: A new porous Zr-based MOF was synthesized by the solvothermal method using 2,6-naphthalenedicarboxylic acid (NDC) as organic linker, and its luminescent performance stability were investigated systematically. The material exhibits quite high chemical in addition to exceptional thermal stability, better than existing MOFs. experiments combining with computations indicate that electron transfer from inorganic moieties contributes behavior of Zr-NDC besides NDC ligand. As far we know, this is first study investigating behaviors such Moreover, cycling measurements demonstrate an interesting prospect for long-term reusability material. results obtained work may provide useful information design physicochemically stable MOFs permanent porosity sensing applications future.
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