Extraction of Rare Earth Elements(III) with Mixtures of Some New Tridentate Carbamoylmethylphosphine Oxides and 4-Benzoyl-3-methyl-1-phenyl-1 H -pyrazol-5(4 H )-one from Hydrochloric Acid Solutions

作者: O. I. Artyushin , V. K. Karandashev , N. A. Bondarenko , A. N. Turanov , V. A. Khvostikov

DOI: 10.1134/S1070363221030075

关键词:

摘要: Extraction of rare earths(III) from hydrochloric acid solutions with mixtures new tridentate carbamoylmethylphosphine oxides Ph2P(O)CH2CON(R)CH2CH2P(O)Ph2 (R = Me, Bu, Oct) and 4-benzoyl-3-methyl-1-phenyl-1H-pyrazol-5(4H)-one in organic solvents has been studied. The observed strong synergistic effect attributed to the formation hydrophobic mixed-ligand earth complexes phase. Stoichiometry extractable determined, extraction constants have calculated. solvent composition aqueous phase on efficiency analyzed.

参考文章(23)
E. Philip Horwltz, Kathleen A. Martin, Herbert Diamond, Louis Kaplan, EXTRACTION OF Am FROM NITRIC ACID BY CARBAMOYL-PHOSPHORYL EXTRACTANTS: THE INFLUENCE OF SUBSTITUENTS ON THE SELECTIVITY OF Am OVER Fe AND SELECTED FISSION PRODUCTS Solvent Extraction and Ion Exchange. ,vol. 4, pp. 449- 494 ,(1986) , 10.1080/07366298608917877
Andrew H. Bond, Mark L. Dietz, Renato Chiarizia, Incorporating Size Selectivity into Synergistic Solvent Extraction: A Review of Crown Ether-Containing Systems Industrial & Engineering Chemistry Research. ,vol. 39, pp. 3442- 3464 ,(2000) , 10.1021/IE000356J
V. M. Jordanov, M. Atanassova, I. L. Dukov, SOLVENT EXTRACTION OF LANTHANIDES WITH 1-PHENYL-3-METHYL-4-BENZOYL-5-PYRAZOLONE Separation Science and Technology. ,vol. 37, pp. 3349- 3356 ,(2002) , 10.1081/SS-120006166
A. N. Turanov, V. K. Karandashev, E. V. Sharova, O. I. Artyushin, I. L. Odinets, Extraction of rare earth elements(III) from HNO3 and HCl solutions with mixtures of carbamoylmethylphosphine oxides and picrolonic acid Radiochemistry. ,vol. 55, pp. 203- 207 ,(2013) , 10.1134/S1066362213020100
Kenneth L. Nash, Mark P. Jensen, ANALYTICAL-SCALE SEPARATIONS OF THE LANTHANIDES: A REVIEW OF TECHNIQUES AND FUNDAMENTALS Separation Science and Technology. ,vol. 36, pp. 1257- 1282 ,(2001) , 10.1081/SS-100103649
Kenichi Akiba, Mikio Wada, Takuji Kanno, Effect of diluent on synergic extraction of europium by thenoyltrifluoroacetone and tri-n-octyl phosphine oxide Journal of Inorganic and Nuclear Chemistry. ,vol. 43, pp. 1031- 1034 ,(1981) , 10.1016/0022-1902(81)80169-8
T. Ya. Medved', M. K. Chmutova, N. P. Nesterova, O. �. Koiro, N. E. Kochetkova, B. F. Myasoedov, M. I. Kabachnik, Oxides of dialkyl(diaryl)[dialkylcarbamoylmethyl]phosphines Russian Chemical Bulletin. ,vol. 30, pp. 1743- 1747 ,(1981) , 10.1007/BF00949488
B.F. Myasoedov, M.K. Chmutova, N.E. Kochetkova, O.E. Koiro, G.A. Pribylova, N.P. Neeterova, T.Ya. Medved, M.I. Kabachnik, [DIALKYLCARBAMOYLMETHYL] PHOSPHINE OXIDES ON THEIR EXTRACTION CAPACITY AND SELECTIVITY Solvent Extraction and Ion Exchange. ,vol. 4, pp. 61- 81 ,(1986) , 10.1080/07366298608917853
Emil Tashev, Maria Atanassova, Sabi Varbanov, Tania Tosheva, Stoycho Shenkov, Anne-Sophie Chauvin, Ivan Dukov, Synthesis of octa(1,1,3,3-tetramethylbutyl)octakis(dimethylphosphinoylmethyleneoxy)calix[8]arene and its application in the synergistic solvent extraction and separation of lanthanoids Separation and Purification Technology. ,vol. 64, pp. 170- 175 ,(2008) , 10.1016/J.SEPPUR.2008.09.011