Non-thermal process for extracting rare earths from bastnaesite by means of mechanochemical treatment

作者: Qiwu Zhang , Fumio Saito

DOI: 10.1016/S0304-386X(97)00048-0

关键词:

摘要: A novel process for extracting rare earths such as Ce, La contained in bastnaesite mineral (ReCO33F, Re = earths) has been developed this work. This is composed of three steps. The first step milling the mixture and NaOH powders, forming mechanochemically Re(OH)3 Na compounds. second washing ground with water, removing soluble third leaching washed powder HCl or H2SO4 solutions at room temperature, earths. extractive yield improved an increase time. Furthermore, solution superior to a medium. In present work, more than 90% sample was extracted by dilute from milled 120 min.

参考文章(9)
W. John Williams, Handbook of anion determination ,(1979)
Pol Duwez, Frank H. Brown, Francis Odell, The Zirconia-Yttria System Journal of The Electrochemical Society. ,vol. 98, pp. 356- 362 ,(1951) , 10.1149/1.2778219
C. L. Luke, Determination of Traces of Boron in Silicon, Germanium, and Germanium Dioxide Analytical Chemistry. ,vol. 27, pp. 1150- 1153 ,(1955) , 10.1021/AC60103A031
Toshio Iijima, Kazuhiro Kato, Toyohiko Kuno, Akitsugu Okuwaki, Yoshiaki Umetsu, Taijiro Okabe, Cerium concentrate and mixed rare earth chloride by the oxidative decomposition of bastnaesite in molten sodium hydroxide Industrial & Engineering Chemistry Research. ,vol. 32, pp. 733- 737 ,(1993) , 10.1021/IE00016A021
Alan S. Hallsworth, John A. Weatherell, Dan. Deutsch, Determination of subnanogram amounts of fluoride with the fluoride electrode. Analytical Chemistry. ,vol. 48, pp. 1160- ,(1976) , 10.1021/AC50006A009
Qiwu Zhang, Fumio Saito, Mechanochemical Processing of Celestine Chemical Engineering Journal. ,vol. 66, pp. 79- 82 ,(1997) , 10.1016/S1385-8947(96)03181-6
Adrian H. Daane, Chemistry of the Rare-Earth Elements. Journal of the American Chemical Society. ,vol. 88, pp. 5938- 5938 ,(1966) , 10.1021/JA00976A049
Shigeru MUKAI, Mineral Processing and Refining of Rare Earth Elements Tetsu To Hagane-journal of The Iron and Steel Institute of Japan. ,vol. 71, pp. 633- 644 ,(1985) , 10.2355/TETSUTOHAGANE1955.71.6_633