Rotational contour analysis of bands in the 313 nm electronic spectrum of isoquinoline: Evidence for ππ* character and coriolis coupling
作者： Karim H. Hassan , J.Michael Hollas
DOI: 10.1016/0301-0104(89)85016-5
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摘要: Abstract The A 1A″ (nπ*) and B 1A′ (ππ*) states of isoquinoline are only 1106 cm−1 apart strongly coupled through out-of-plane vibrations. Computer simulation rotational contours confirms the 000(ππ*) assignment shows that there is appreciable Coriolis coupling in a01(nπ*) b01 bands, where νa νb involved vibronic to ππ* state.
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