Photovoltaic properties and exciplex emission of polyphenylenevinylene-based blend solar cells

作者: Chunhong Yin , Thomas Kietzke , Dieter Neher , Hans-Heinrich Hörhold

DOI: 10.1063/1.2710474

关键词:

摘要: By studying the photoluminescence emission and photovoltaic properties of blends polyphenylenevinylene (PPV)-based electron donating accepting polymers, authors observed a strict anticorrelation between relative exciplex in solid state efficiency corresponding blend devices. Comparative studies on defined bilayer geometries showed that overall shape current-voltage characteristics under illumination is independent device geometry layer thickness. Consequently, they conclude photocurrent PPV-based mainly determined by to form free carriers rather than carrier recombination.

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