Catalyst composition for direct conversion of ethanol to propylene

作者: Andrzej M. Malek , Yu Liu , Albert E. Schweizer

DOI:

关键词:

摘要: A process to prepare propylene showing desirably increased selectivity comprises contacting, at an elevated temperature, ethanol and a rhenium oxide-modified ZSM-5 zeolite catalyst, under conditions suitable form propylene. The catalyst may be prepared by impregnating, in aqueous or organic medium, with source, precursor, calcining the precursor catalyst.

参考文章(23)
H. Hamdan, Z. Ramli, Structural Characterization of Rhenium Impregnated Zeolite Y and ZSM-5 by 29Si and 27 Al MAS NMR and IR Spectroscopy Zeolites and Microporous Crystals, Proceedings of the International Symposium on Zeolites and Microporous Crystals. ,vol. 83, pp. 125- 132 ,(1994) , 10.1016/S0167-2991(08)63250-4
Johan Adriaan Martens, Johannes Petrus Verduijn, Luc Roger Marc Martens, Zsm-5 zeolite ,(1993)
Shivanand Janardan Kulkarni, Kondapuram Vijay Raghavan, Narender Nama, Srinivasu Pavuuri, Process for the preparation of zsm-5 catalyst ,(2002)
Stephen J. Miller, Method for making zsm-5 zeolites ,(2000)
Gary M. Smith, Barry K. Speronello, ZSM-5 Additive ,(2008)
Michiaki Umeno, Daisuke Mochizuki, Toshihiro Takai, Method of producing propylene containing biomass-origin carbon ,(2006)
Mikio Hayashi, Toru Setoyama, Yumiko Yoshikawa, Takahiko Takewaki, 正志 山口, 隆彦 武脇, 由美子 吉川, 幹夫 林, Masashi Yamaguchi, 亨 瀬戸山, チンチュイン ジュー, Chinchuin Juu, Method for producing propylene ,(2004)
Jiang Zhao, Zhongneng Liu, Xinghua Jiang, Deju Wang, Process for producing binder-free ZSM-5 zeolite in small crystal size ,(2006)
Mingting Xu, John Macaoay, In-situ ZSM-5 synthesis ,(2004)