Investigation of an electroactive immobilized azomethine for potential electrochromic use

作者: Monika Wałęsa-Chorab , W.G. Skene

DOI: 10.1016/J.SOLMAT.2019.109977

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摘要: Abstract An electroactive small molecule consisting of three triphenylamines and two azomethines was prepared with a pendant oxetane moiety. The immobilized on transparent electrodes by photochemically mediated acid catalyzed ring-opening polymerization the oxetane. Positive negative patterns polymer films could also be copolymerizing azomethine monomer trioxetane cross-linker. resulting cross-linked reversibly switched between their neutral oxidized states applied electrochemical potentials for upwards 80 min. colors yellow (400 nm) purple (upwards 790 nm) when applying an potential ca. 100 mV 1.1 V vs. Ag o , respectively. thickness film varied 200 1000 nm 700 nm having optimal electrochromic performance.

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