Synthesis and thermal transformations of allyl aryl ethers of adamantane series
作者： M. R. Baimuratov , M. V. Leonova , Yu. N. Klimochkin
DOI: 10.1134/S1070363214040057
关键词:
摘要: Allyl aryl ethers of adamantane series were obtained by reacting (E)-1-(adamant-1-yl)-3-bromoprop-1-ene with phenol or ethyl salicylate. The features thermal transformations allyl containing bulky scaffold investigated. It has been found that the composition reaction products is largely dependent on temperature, time and nature solvent. When a nucleophilic solvent was used, proceeded via formal substitution phenoxy fragment species prevailing in medium.
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