作者: Elliott H. Lieb , Jakob Yngvason
DOI: 10.1016/S0370-1573(98)00082-9
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摘要: The essential postulates of classical thermodynamics are formulated, from which the second law is deduced as principle increase entropy in irreversible adiabatic processes that take one equilibrium state to another. constructed here defined only for states and no attempt made define it otherwise. Statistical mechanics does not enter these considerations. One main concepts makes everything work comparison (which, essence, given any two same chemical composition at least adiabatically accessible other) we show can be derived some assumptions about pressure thermal equilibrium. Temperature entropy, but start even concept `hotness' assumed. Our formulation offers a certain clarity rigor goes beyond most textbook discussions law.