Gasphasen‐Reaktionen, 24. Die thermische Erzeugung von Thiocarbonyl‐Verbindungen
作者： Hans Bock , Takakuni Hirabayashi , Shamsher Mohmand
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摘要: Thiocarbonyl-Derivate R1R2C=S mit R1, R2 = H, CH3, C6H5 lassen sich in der Gasphase thermisch aus vielerlei Ausgangsverbindungen erzeugen; vorteilhaft sind insbesondere die Propen-Abspaltung Allylsulfiden oder fur ihre Reindarstellung Pyrolyse von Dithietan- und Trithiolan-Derivaten. Die Photoelektronen-Spektroskopie bewahrt zur Gasanalyse im verwendeten Stromungsrohr, Optimierung Zersetzungsbedingungen uber Zuordnung beobachteten Ionisierungsmuster Charakterisierung hergestellten Thioaldehyde Thioketone.
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