Ideal hydrogen termination of the Si (111) surface

作者: G. S. Higashi , Y. J. Chabal , G. W. Trucks , Krishnan Raghavachari

DOI: 10.1063/1.102728

关键词:

摘要: Aqueous HF etching of silicon surfaces results in the removal surface oxide and leaves behind terminated by atomic hydrogen. The effect varying solution pH on structure is studied measuring SiH stretch vibrations with infrared absorption spectroscopy. Basic solutions ( pH=9–10) produce ideally Si(111) monohydride ( 3/4 SiH) oriented normal to surface. found be very homogeneous low defect density (<0.5%) narrow vibrational linewidth (0.95 cm−1 ).

参考文章(17)
M. Grundner, R. Schulz, The surface state of Si (100) and (111) wafers after treatment with hydrofluoric acid Deposition and Growth: Limits for Microelectronics. ,vol. 167, pp. 329- 337 ,(2008) , 10.1063/1.37163
F.J. Grunthaner, P.J. Grunthaner, Chemical and electronic structure of the SiO2/Si interface Materials Science Reports. ,vol. 1, pp. 65- 160 ,(1986) , 10.1016/S0920-2307(86)80001-9
Y. J. Chabal, Krishnan Raghavachari, Surface infrared study of Si(100)-(2×1)H Physical Review Letters. ,vol. 53, pp. 282- 285 ,(1984) , 10.1103/PHYSREVLETT.53.282
Y.J. Chabal, Surface infrared spectroscopy Surface Science Reports. ,vol. 8, pp. 211- 357 ,(1988) , 10.1016/0167-5729(88)90011-8
N. J. Harrick, Internal reflection spectroscopy ,(1967)
Z. Schlesinger, L. H. Greene, A. J. Sievers, Dipole-dipole-interaction-induced line narrowing in thin-film vibrational-mode spectra Physical Review B. ,vol. 32, pp. 2721- 2723 ,(1985) , 10.1103/PHYSREVB.32.2721
E. Yablonovitch, D. L. Allara, C. C. Chang, T. Gmitter, T. B. Bright, Unusually low surface-recombination velocity on silicon and germanium surfaces. Physical Review Letters. ,vol. 57, pp. 249- 252 ,(1986) , 10.1103/PHYSREVLETT.57.249
J. C. Tully, Y. J. Chabal, Krishnan Raghavachari, J. M. Bowman, R. R. Lucchese, Infrared linewidths and vibrational lifetimes at surfaces: H on Si(100) Physical Review B. ,vol. 31, pp. 1184- 1186 ,(1985) , 10.1103/PHYSREVB.31.1184
H. Kobayashi, K. Edamoto, M. Onchi, M. Nishijima, Reactions of atomic hydrogen with the Si(111) (7×7) surface by high resolution electron energy loss spectroscopy Journal of Chemical Physics. ,vol. 78, pp. 7429- 7436 ,(1983) , 10.1063/1.444733