作者: G. S. Higashi , Y. J. Chabal , G. W. Trucks , Krishnan Raghavachari
DOI: 10.1063/1.102728
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摘要: Aqueous HF etching of silicon surfaces results in the removal surface oxide and leaves behind terminated by atomic hydrogen. The effect varying solution pH on structure is studied measuring SiH stretch vibrations with infrared absorption spectroscopy. Basic solutions ( pH=9–10) produce ideally Si(111) monohydride ( 3/4 SiH) oriented normal to surface. found be very homogeneous low defect density (<0.5%) narrow vibrational linewidth (0.95 cm−1 ).