Plasma deposition of vinyl acetate onto Nylon-4 membrane for pervaporation and evapomeation separation of aqueous alcohol mixtures

作者: Kueir-Rarn Lee , Rong-Yuh Chen , Juin-Yih Lai

DOI: 10.1016/0376-7388(92)80015-C

关键词:

摘要: Pervaporation and evapomeation separations of water-alcohol mixtures through a modified Nylon-4 membrane - coated with plasma deposited, hydrolyzed vinyl acetate (VAc) (PVA-p-N4), were investigated. The effects downstream pressure, deposition conditions, feed composition, temperature, size the alcohols on performance PVA-p-N4 membranes studied. separation factor permeation rate this are both higher than those unmodified for pervaporation aqueous ethanol solutions. A 13.5 420 g/m2-hr can be obtained. Compared pervaporation, effectively increases mixtures, while is decreased.

参考文章(18)
Soo Kang Yong, Wook Lee Sang, Young Kim Un, Sup Shim Jyong, Pervaporation of water-ethanol mixtures through crosslinked and surface-modified poly(vinyl alcohol) membrane Journal of Membrane Science. ,vol. 51, pp. 215- 226 ,(1990) , 10.1016/S0376-7388(00)80904-7
Akira Mochizuki, Shigetoshi Amiya, Yoshio Sato, Hisashi Ogawara, Shuzo Yamashita, Pervaporation separation of water/ethanol mixtures through polysaccharide membranes. IV, The relationships between the permselectivity of alginic acid membrane and its solid state structure Journal of Applied Polymer Science. ,vol. 40, pp. 385- 400 ,(1990) , 10.1002/APP.1990.070400307
J. Y. Lai, T. C. Chang, Z. J. Wu, T. S. Hsieh, Vinyl monomer irradiation‐grafted nylon 4 membranes Journal of Applied Polymer Science. ,vol. 32, pp. 4709- 4718 ,(1986) , 10.1002/APP.1986.070320435
Kenneth C. Hoover, Sun-Tak Hwang, Pervaporation by a continuous membrane column Journal of Membrane Science. ,vol. 10, pp. 253- 271 ,(1982) , 10.1016/S0376-7388(00)81413-1
Toshihiro Hirotsu, Water‐ethanol separation by pervaporation through plasma graft polymerized membranes Journal of Applied Polymer Science. ,vol. 34, pp. 1159- 1172 ,(1987) , 10.1002/APP.1987.070340324
Robert Binning, Robert Lee, Joseph Jennings, Eugene Martin, Separation of Liquid Mixtures by Permeation Industrial & Engineering Chemistry. ,vol. 53, pp. 45- 50 ,(1961) , 10.1021/IE50613A030
J. Y. Lai, C. Y. Shih, S. M. Tsai, Plasma deposition modified nylon 4 membranes for hemodialysis Journal of Applied Polymer Science. ,vol. 43, pp. 1431- 1440 ,(1991) , 10.1002/APP.1991.070430804