An Introduction to the Solid State Polymerization of Transition-Metal Complexes: A Comparative Study.

作者: K. Cheng , B. M. Foxman , S. W. Gersten

DOI: 10.1080/00268947908071723

关键词:

摘要: Abstract Preliminary studies in this laboratory' of topochemical and topotactic polyreactions NiBr2[P(CH2CH2CN)3]2 have shown that the reactions are many cases characterized by a) product specificity, b) stereospecificity, c) “crystallographic specificity” d) highly anisotropic “front motion” through individual single crystals. The polymerization reaction under investigation here is

参考文章(7)
B. Wunderlich, Kristallisation während der Polymerisation Angewandte Chemie. ,vol. 80, pp. 1009- 1016 ,(1968) , 10.1002/ANGE.19680802402
R. H. Baughman, Solid-state synthesis of large polymer single crystals Journal of Polymer Science Part B. ,vol. 12, pp. 1511- 1535 ,(1974) , 10.1002/POL.1974.180120801
J. Zanos Gougoutas, Templates and Twinning in Topotaxy Israel Journal of Chemistry. ,vol. 10, pp. 395- 406 ,(1972) , 10.1002/IJCH.197200042
R. Mateva, G. Wegner, G. Lieser, Growth of polyoxymethylene crystals during cationic polymerization of trioxane in nitrobenzene Journal of Polymer Science: Polymer Letters Edition. ,vol. 11, pp. 369- 376 ,(1973) , 10.1002/POL.1973.130110605
Kent Cheng, Bruce M. Foxman, Polymerization of dibromobis[tris(2-cyanoethyl)phosphine]nickel: a "triply-specific" solid-state reaction Journal of the American Chemical Society. ,vol. 99, pp. 8102- 8103 ,(1977) , 10.1021/JA00466A080