Hydrothermal saline promoted grafting: a route to sulfonic acid SBA-15 silica with ultra-high acid site loading for biodiesel synthesis
作者： C. Pirez , A. F. Lee , J. C. Manayil , C. M. A. Parlett , K. Wilson
DOI: 10.1039/C4GC01139B
关键词:
摘要: A simple grafting protocol is reported which affords a ten-fold enhancement in acid site density of mesoporous sulfonic silicas compared to conventional syntheses, offering improved process efficiency and new opportunities for tailored supported solid acids sustainable chemistry.
rsc.org
sci-hub.se 参考文章(30)
Alexandra Simperler, Robert G. Bell, Michael W. Anderson, Probing the Acid Strength of Brønsted Acidic Zeolites with Acetonitrile: Quantum Chemical Calculation of 1H, 15N, and 13C NMR Shift Parameters Journal of Physical Chemistry B. ,vol. 108, pp. 7142- 7151 ,(2004) , 10.1021/JP035674L
Karen Wilson, Adam F Lee, Duncan J Macquarrie, James H Clark, Structure and reactivity of sol-gel sulphonic acid silicas Applied Catalysis A-general. ,vol. 228, pp. 127- 133 ,(2002) , 10.1016/S0926-860X(01)00956-5
Yaohui Feng, Benqiao He, Yuhe Cao, Jianxin Li, Meng Liu, Feng Yan, Xiaoping Liang, Biodiesel production using cation-exchange resin as heterogeneous catalyst Bioresource Technology. ,vol. 101, pp. 1518- 1521 ,(2010) , 10.1016/J.BIORTECH.2009.07.084
J. P. Dacquin, A. F. Lee, C. Pirez, K. Wilson, Pore-expanded SBA-15 sulfonic acid silicas for biodiesel synthesis Chemical Communications. ,vol. 48, pp. 212- 214 ,(2012) , 10.1039/C1CC14563K
Jérémy Dhainaut, Jean-Philippe Dacquin, Adam F. Lee, Karen Wilson, Hierarchical macroporous–mesoporous SBA-15 sulfonic acidcatalysts for biodiesel synthesis Green Chem.. ,vol. 12, pp. 296- 303 ,(2010) , 10.1039/B919341C
Cyril Pirez, Jean-Michel Caderon, Jean-Philippe Dacquin, Adam F. Lee, Karen Wilson, Tunable KIT-6 Mesoporous Sulfonic Acid Catalysts for Fatty Acid Esterification ACS Catalysis. ,vol. 2, pp. 1607- 1614 ,(2012) , 10.1021/CS300161A
Shih-Yuan Chen, Toshiyuki Yokoi, Chih-Yuan Tang, Ling-Yun Jang, Takashi Tatsumi, Jerry C. C. Chan, Soofin Cheng, Sulfonic acid-functionalized platelet SBA-15 materials as efficient catalysts for biodiesel synthesis Green Chemistry. ,vol. 13, pp. 2920- 2930 ,(2011) , 10.1039/C1GC15299H
Roberto Rinaldi, Ferdi Schüth, Design of solid catalysts for the conversion of biomass Energy and Environmental Science. ,vol. 2, pp. 610- 626 ,(2009) , 10.1039/B902668A
Juan A Melero, L Fernando Bautista, Gabriel Morales, Jose Iglesias, Rebeca Sánchez-Vázquez, None, Biodiesel production from crude palm oil using sulfonic acid-modified mesostructured catalysts Chemical Engineering Journal. ,vol. 161, pp. 323- 331 ,(2010) , 10.1016/J.CEJ.2009.12.037
Paul T Anastas, Lauren B Bartlett, Mary M Kirchhoff, Tracy C Williamson, None, The role of catalysis in the design, development, and implementation of green chemistry Catalysis Today. ,vol. 55, pp. 11- 22 ,(2000) , 10.1016/S0920-5861(99)00222-9