The dehydrogenation of alcohols through a concerted bimetallic mechanism involving an amido-bridged diiridium complex.
作者： Inmaculada Mena , Miguel A. Casado , Víctor Polo , Pilar García-Orduña , Fernando J. Lahoz
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摘要: Financial support from the CONSOLIDER INGENIO-2010 program under projects MULTICAT (CSD2009-00050) and Factoria de Cristalizacion (CSD2006-0015), DGA-ESF are acknowledged. P.G.O. acknowledges financial CSIC “JAE-Doc” program, a contract co-funded by ESF.
sci-hub.se 参考文章(70)
Gerard Parkin, Allan Van Asselt, David J. Leahy, LeRoy Whinnery, Nhi G. Hua, Roger W. Quan, Lawrence M. Henling, William P. Schaefer, Bernard D. Santarsiero, John E. Bercaw, Oxo-hydrido and imido-hydrido derivatives of permethyltantalocene. Structures of (.eta.5-C5Me5)2Ta(:O)H and (.eta.5-C5Me5)2Ta(:NC6H5)H: doubly or triply bonded tantalum oxo and imido ligands? Inorganic Chemistry. ,vol. 31, pp. 82- 85 ,(1992) , 10.1021/IC00027A016
Jing Zhao, Alan S Goldman, John F Hartwig, Oxidative Addition of Ammonia to Form a Stable Monomeric Amido Hydride Complex Science. ,vol. 307, pp. 1080- 1082 ,(2005) , 10.1126/SCIENCE.1109389
Chengbao Ni, Hao Lei, Philip P. Power, Reaction of M(II) Diaryls (M = Mn or Fe) with Ammonia to Afford Parent Amido Complexes Organometallics. ,vol. 29, pp. 1988- 1991 ,(2010) , 10.1021/OM1000502
Cristina Tejel, You-Mao Shi, Miguel A. Ciriano, Andrew J. Edwards, Fernando J. Lahoz, Luis A. Oro, REVERSIBLE FORMATION OF RAFTLIKE ORGANOIMIDOTETRARHODIUM CLUSTERS BY THE MIGRATION OF RHLN+ FRAGMENTS Angewandte Chemie. ,vol. 35, pp. 1516- 1518 ,(1996) , 10.1002/ANIE.199615161
Claudia M. Fafard, Debashis Adhikari, Bruce M. Foxman, Daniel J. Mindiola, Oleg V. Ozerov, Addition of Ammonia, Water, and Dihydrogen Across a Single Pd−Pd Bond Journal of the American Chemical Society. ,vol. 129, pp. 10318- 10319 ,(2007) , 10.1021/JA0731571
Bjorn Askevold, Jorge Torres Nieto, Samat Tussupbayev, Martin Diefenbach, Eberhardt Herdtweck, Max C. Holthausen, Sven Schneider, Ammonia formation by metal–ligand cooperative hydrogenolysis of a nitrido ligand Nature Chemistry. ,vol. 3, pp. 532- 537 ,(2011) , 10.1038/NCHEM.1051
Sebastian Imm, Sebastian Bähn, Min Zhang, Lorenz Neubert, Helfried Neumann, Florian Klasovsky, Jan Pfeffer, Thomas Haas, Matthias Beller, Improved Ruthenium-Catalyzed Amination of Alcohols with Ammonia: Synthesis of Diamines and Amino Esters Angewandte Chemie International Edition. ,vol. 50, pp. 7599- 7603 ,(2011) , 10.1002/ANIE.201103199
Hiroko Arita, Koji Ishiwata, Shigeki Kuwata, Takao Ikariya, Acid–Base Bifunction and Umpolung of the Bridging Hydride in a Coordinatively Unsaturated Mesylimido- and Hydrido-Bridged Diiridium Complex Organometallics. ,vol. 27, pp. 493- 496 ,(2008) , 10.1021/OM7009705
Joel S. Freundlich, Richard R. Schrock, William M. Davis, Synthetic and Mechanistic Investigations of Trimethylsilyl-Substituted Triamidoamine Complexes of Tantalum That Contain Metal−Ligand Multiple Bonds Journal of the American Chemical Society. ,vol. 118, pp. 3643- 3655 ,(1996) , 10.1021/JA953826N
Paul R. Sharp, Oxo and imido ligands in late transition metal chemistry Journal of The Chemical Society-dalton Transactions. pp. 2647- 2657 ,(2000) , 10.1039/B002556I