Phonon coupled cooperative low-spin 1A1high-spin 5T2 transition in [Fe(phen)2(NCS)2] and [Fe(phen)2(NCSe)2] crystals
作者： M. Sorai , S. Seki
DOI: 10.1016/S0022-3697(74)80010-7
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摘要: Heat capacities of [Fe(phen) 2 (NCS) 2 ] and [Fe(phen) 2 (NCSe) 2 ] were measured between 13 5 and 375 K. A heat capacity anomaly due to the spin-transition from low-spin 1 A 1 to …
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E. K�nig, A. S. Chakravarty, K. Madeja, Magnetic properties of transition metal ion cubic 5T2 terms in axial ligand fields Theoretical Chemistry Accounts. ,vol. 9, pp. 171- 181 ,(1967) , 10.1007/BF00529950
K. Madeja, W. Wilke, S. Schmidt, Methoden zur Darstellung von Diacido-bis-1,10-phenanthrolin-Eisen(II)-Komplexen Zeitschrift für anorganische und allgemeine Chemie. ,vol. 346, pp. 306- 315 ,(1966) , 10.1002/ZAAC.19663460511
D. B. Chesnut, Simple Model for Some Dense Magnetic Exciton Systems Journal of Chemical Physics. ,vol. 40, pp. 405- 411 ,(1964) , 10.1063/1.1725127
D. C. Fisher, H. G. Drickamer, Effect of Pressure on the Spin State of Iron in Ferrous Phenanthroline Compounds The Journal of Chemical Physics. ,vol. 54, pp. 4825- 4837 ,(1971) , 10.1063/1.1674758
Edgar Koenig, K. Madeja, 5T2-1A1 Equilibriums in some iron(II)-bis(1,10-phenanthroline) complexes Inorganic Chemistry. ,vol. 6, pp. 48- 55 ,(1967) , 10.1021/IC50047A011
E. König, G. Ritter, B. Braunecker, K. Madeja, H. A. Goodwin, F. E. Smith, Mößbauer‐Effekt‐Untersuchungen bei Änderung des Grundzustandes: 5 T2‐1 A1‐„Spin‐Gleichgewichte”︁ in Tris(2‐methyl‐1,10‐phenanthrolin)Eisen(II)‐Komplexen Berichte der Bunsengesellschaft für physikalische Chemie. ,vol. 76, pp. 393- 400 ,(1972) , 10.1002/BBPC.19720760506
L. Sacconi, Conformational and spin state interconversions in transition metal complexes Pure and Applied Chemistry. ,vol. 27, pp. 161- 192 ,(1971) , 10.1351/PAC197127010161
E. König, K. Madeja, Infra-red spectra at the 5T2-1A1 cross-over in iron (II) complexes Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy. ,vol. 23, pp. 45- 54 ,(1967) , 10.1016/0584-8539(67)80206-X
James H. Takemoto, Bennett Hutchinson, Effect of magnetic crossover on the low-frequency IR spectrum of [Fe(1,10-phenanthroline)2(NCS)2] Inorganic and Nuclear Chemistry Letters. ,vol. 8, pp. 769- 772 ,(1972) , 10.1016/0020-1650(72)80152-1
James H. Takemoto, Bennett Hutchinson, Low-frequency infrared spectra of complexes which exhibit magnetic crossover. I. Iron(II) complexes of 1,10-phenanthroline and 2,2'-bipyridine Inorganic Chemistry. ,vol. 12, pp. 705- 708 ,(1973) , 10.1021/IC50121A049