EPR studies of manganese centers in SrTiO3: Non-Kramers Mn3+ ions and spin-spin coupled Mn4+ dimers

作者: A. Dejneka , L. Jastrabik , J. Lancok , D. V. Azamat , V. A. Trepakov

DOI: 10.1063/1.4723653

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摘要: X- and Q-band electron paramagnetic resonance (EPR) study is reported on the SrTiO3 single crystals doped with 0.5-at.% MnO. EPR spectra originating from S = 2 ground state of Mn3+ ions are shown to belong three distinct types Jahn-Teller centres. The ordering oxygen vacancies due reduction treatment samples consequent formation vacancy associated centres explained in terms localized charge compensation. SrTiO3: Mn show presence next nearest neighbor exchange coupled Mn4+ pairs directions.

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