Cobalt phosphide as a highly active non-precious metal cocatalyst for photocatalytic hydrogen production under visible light irradiation
作者： Shuang Cao , Yong Chen , Chun-Chao Hou , Xiao-Jun Lv , Wen-Fu Fu
DOI: 10.1039/C4TA07149B
关键词:
摘要: Cobalt phosphide (Co2P) is found, for the first time, to be a novel cocatalyst efficient photocatalytic hydrogen evolution system containing CdS nanorods as photocatalyst and DL-mandelic acid an electron donor in water. Under optimal conditions, H2-production rate can reach up 19 373 μmolh−1 g−1 after 10 h of LED light irradiation. Meanwhile, oxidized benzoylformic by photo-generated holes nanorods, providing green economic way synthesize from acid.
rsc.org
sci-hub.se 参考文章(40)
Peng Xiao, Mahasin Alam Sk, Larissa Thia, Xiaoming Ge, Rern Jern Lim, Jing-Yuan Wang, Kok Hwa Lim, Xin Wang, Molybdenum phosphide as an efficient electrocatalyst for the hydrogen evolution reaction Energy and Environmental Science. ,vol. 7, pp. 2624- 2629 ,(2014) , 10.1039/C4EE00957F
Cheng-Bo Li, Zhi-Jun Li, Shan Yu, Ge-Xia Wang, Feng Wang, Qing-Yuan Meng, Bin Chen, Ke Feng, Chen-Ho Tung, Li-Zhu Wu, Interface-directed assembly of a simple precursor of [FeFe]–H2ase mimics on CdSe QDs for photosynthetic hydrogen evolution in water Energy and Environmental Science. ,vol. 6, pp. 2597- 2602 ,(2013) , 10.1039/C3EE40992A
Jongnam Park, Bonil Koo, Ki Youl Yoon, Yosun Hwang, Misun Kang, Je-Geun Park, Taeghwan Hyeon, Generalized synthesis of metal phosphide nanorods via thermal decomposition of continuously delivered metal-phosphine complexes using a syringe pump. Journal of the American Chemical Society. ,vol. 127, pp. 8433- 8440 ,(2005) , 10.1021/JA0427496
Caixian Zhao, Hean Luo, Feng Chen, Ping Zhang, Lanhua Yi, Kuiyi You, A novel composite of TiO2 nanotubes with remarkably high efficiency for hydrogen production in solar-driven water splitting Energy and Environmental Science. ,vol. 7, pp. 1700- 1707 ,(2014) , 10.1039/C3EE43165G
Shuang Cao, Chuan-Jun Wang, Xiao-Jun Lv, Yong Chen, Wen-Fu Fu, A highly efficient photocatalytic H2 evolution system using colloidal CdS nanorods and nickel nanoparticles in water under visible light irradiation Applied Catalysis B-environmental. ,vol. 162, pp. 381- 391 ,(2015) , 10.1016/J.APCATB.2014.07.014
Shuang Cao, Yong Chen, Chuan-Jun Wang, Ping He, Wen-Fu Fu, Highly efficient photocatalytic hydrogen evolution by nickel phosphide nanoparticles from aqueous solution. Chemical Communications. ,vol. 50, pp. 10427- 10429 ,(2014) , 10.1039/C4CC05026F
Jesse D. Benck, Thomas R. Hellstern, Jakob Kibsgaard, Pongkarn Chakthranont, Thomas F. Jaramillo, Catalyzing the Hydrogen Evolution Reaction (HER) with Molybdenum Sulfide Nanomaterials ACS Catalysis. ,vol. 4, pp. 3957- 3971 ,(2014) , 10.1021/CS500923C
Zhongbin Zhuang, Xiaotang Lu, Qing Peng, Yadong Li, Direct synthesis of water-soluble ultrathin CdS nanorods and reversible tuning of the solubility by alkalinity. Journal of the American Chemical Society. ,vol. 132, pp. 1819- 1821 ,(2010) , 10.1021/JA909776G
Shuling Liu, Yitai Qian, Xicheng Ma, Polymer-assisted synthesis of Co2P nanocrystals Materials Letters. ,vol. 62, pp. 11- 14 ,(2008) , 10.1016/J.MATLET.2007.04.061
Kazuhiko Maeda, Kentaro Teramura, Daling Lu, Tsuyoshi Takata, Nobuo Saito, Yasunobu Inoue, Kazunari Domen, Photocatalyst releasing hydrogen from water Nature. ,vol. 440, pp. 295- 295 ,(2006) , 10.1038/440295A