TiO2 based photocatalytic coatings: From nanostructure to functional properties

作者: Anna Luisa Costa , Simona Ortelli , Magda Blosi , Stefania Albonetti , Angelo Vaccari

DOI: 10.1016/J.CEJ.2013.04.037

关键词:

摘要: Abstract The present study shows the results of direct ceramization textile substrates with commercial derived TiO2 nanosols. A deep investigation on relationship between based nanosols and nanocoatings properties their performances in term hydrophilicity photocatalytic efficiency was performed. Five nanosols, differing for starting pH relative agglomerates size were analyzed. hydrophilic behavior catalytic performance coatings supported different (fabric, glass ceramic) assessed related to physicochemical characterization results. described correlations nanoscale (nanostructure or surface chemistry), macroscale (hydrophilicity), as well functional (photocatalytic activity), represents a first attempt provide sound criteria control material by design experiments. dependent aggregation state, is correlated an increase acidity shift i.e.p. towards acid reveals. Such justifies hydrophilicity, consequent stronger interaction water molecules, that occurs when higher amount Ti−O− sites are available. As well, behavior, resulted good agreement: better self-cleaning activity, so providing useful indications scale-up exploitation such application.

参考文章(45)
Kaihong Qi, John H. Xin, Walid A. Daoud, Chee Leung Mak, Functionalizing Polyester Fiber with a Self-Cleaning Property Using Anatase TiO2 and Low-Temperature Plasma Treatment International Journal of Applied Ceramic Technology. ,vol. 4, pp. 554- 563 ,(2007) , 10.1111/J.1744-7402.2007.02168.X
Jiandong Zhuang, Wenxin Dai, Qinfen Tian, Zhaohui Li, Liyan Xie, Jixin Wang, Ping Liu, Xicheng Shi, Donghui Wang, Photocatalytic Degradation of RhB over TiO2 Bilayer Films: Effect of Defects and Their Location Langmuir. ,vol. 26, pp. 9686- 9694 ,(2010) , 10.1021/LA100302M
Deyong Wu, Mingce Long, Low-temperature synthesis of N-TiO2 sol and characterization of N-TiO2 coating on cotton fabrics Surface & Coatings Technology. ,vol. 206, pp. 3196- 3200 ,(2012) , 10.1016/J.SURFCOAT.2012.01.002
Paul Chin, David F. Ollis, Decolorization of organic dyes on Pilkington Activ™ photocatalytic glass Catalysis Today. ,vol. 123, pp. 177- 188 ,(2007) , 10.1016/J.CATTOD.2007.01.069
Hongping Xiang, Jianfeng Ge, Shaohui Cheng, Hongmei Han, Shaowei Cui, Synthesis and characterization of titania/MQ silicone resin hybrid nanocomposite via sol–gel process Journal of Sol-Gel Science and Technology. ,vol. 59, pp. 635- 639 ,(2011) , 10.1007/S10971-011-2538-0
M. Bellardita, A. Di Paola, L. Palmisano, F. Parrino, G. Buscarino, R. Amadelli, Preparation and photoactivity of samarium loaded anatase, brookite and rutile catalysts Applied Catalysis B-environmental. ,vol. 104, pp. 291- 299 ,(2011) , 10.1016/J.APCATB.2011.03.016
A. Bozzi, T. Yuranova, I. Guasaquillo, D. Laub, J. Kiwi, Self-cleaning of modified cotton textiles by TiO2 at low temperatures under daylight irradiation Journal of Photochemistry and Photobiology A: Chemistry. ,vol. 174, pp. 156- 164 ,(2005) , 10.1016/J.JPHOTOCHEM.2005.03.019
S Ganjoo, R Azimirad, O Akhavan, A Z Moshfegh, Persistent superhydrophilicity of sol-gel derived nanoporous silica thin films Journal of Physics D. ,vol. 42, pp. 025302- ,(2009) , 10.1088/0022-3727/42/2/025302