Hypervalent organoiodine compounds: from reagents to valuable building blocks in synthesis.

作者: Gwendal Grelier , Benjamin Darses , Philippe Dauban

DOI: 10.3762/BJOC.14.128

关键词:

摘要: Most of the polyvalent organoiodine compounds derive from iodoarenes, which are released in stoichiometric amounts any reaction mediated by λ3- or λ5-iodanes. In parallel to development solid-supported reagents reactions catalytic iodine, a third strategy has emerged address this issue terms sustainability. The atom-economy transformations involving λ5-iodanes, thus, been improved designing tandem that allows for incorporating aryl motif into products through subsequent one-pot nucleophilic addition coupling reaction. This review summarizes main achievements reported area.

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