Comparative studies on closure approximations in flows of liquid crystal polymers: I. elongational flows

作者: Qi Wang

DOI: 10.1016/S0377-0257(97)00031-1

关键词:

摘要: Abstract We derive nine approximate models for flows of liquid crystal polymers by applying different closure approximations to the kinetic theory developed Bhave et al. then benchmark comparing their uniaxial steady state solutions corresponding ones in elongational flows. For prolate states, we find that all give qualitatively acceptable approximations. In particular, when flow is uniaxially stretching, which flow-orientation interaction term approximated second Hinch-Leal approximation well range small Peclet numbers; likewise, molecule-molecule Doi large numbers. oblate phase, however, except DD (Doi approximation) and DHL2 (Hybrid HL2 model may produce either fictitious or nonphysical states with out-of-range order parameter values. Therefore, caution use this phase. contrast, are applicable phases any numbers polymer concentration addition, they phase biaxially stretching. end, best overall given model.

参考文章(15)
F.M. Leslie, Theory of Flow Phenomena in Liquid Crystals Advances in Liquid Crystals. ,vol. 4, pp. 1- 81 ,(1979) , 10.1016/B978-0-12-025004-2.50008-9
R. Byron Bird, Dynamics of Polymeric Liquids ,(1977)
Masao Doi, Sam F Edwards, The theory of polymer dynamics Oxford University Press. ,(1986)
C. V. Chaubal, L. G. Leal, G. H. Fredrickson, A comparison of closure approximations for the Doi theory of LCPs Journal of Rheology. ,vol. 39, pp. 73- 103 ,(1995) , 10.1122/1.550689
University of Minnesota. Institute for Mathematics and Its Applications, Liquid Crystals with Variable Degree of Orientation Archive for Rational Mechanics and Analysis. ,vol. 113, pp. 97- 120 ,(1991) , 10.1007/BF00380413
Suresh Ramalingam, R. C. Armstrong, Analysis of isothermal spinning of liquid‐crystalline polymers Journal of Rheology. ,vol. 37, pp. 1141- 1169 ,(1993) , 10.1122/1.550374
R. G. Larson, Arrested Tumbling in Shearing Flows of Liquid Crystal Polymers Macromolecules. ,vol. 23, pp. 3983- 3992 ,(1990) , 10.1021/MA00219A020
M. Gregory Forest, Qi Wang, Stephen E. Bechtel, 1-D models for thin filaments of liquid-crystalline polymers: coupling of orientation and flow in the stability of simple solutions Physica D: Nonlinear Phenomena. ,vol. 99, pp. 527- 554 ,(1997) , 10.1016/S0167-2789(96)00173-X