A site-site theory for finite concentration saline solutions
作者： John Perkyns , B. Montgomery Pettitt
DOI: 10.1063/1.463485
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摘要: A liquid state theory based on site–site integral equations is constructed to have the asymptotics given by angular expansion theory. This results in a which shows dielectric consistency, e.g., constant as viewed from solvent same that ions. Such consistency lacking other extended reference interaction site model (XRISM)‐based theories and leads unrealistic structural predictions. The Kirkwood–Buff route thermodynamics used allows physical partitioning of terms responsible for solvation process. Sample 1–1 salt are given.
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